Efficient Adsorption of Trivalent Rare Earth Elements Using Nano Copper Ferrite: Kinetics, Isotherms and Thermodynamics

IF 0.3 Q4 CHEMISTRY, MULTIDISCIPLINARY Oriental Journal Of Chemistry Pub Date : 2023-12-27 DOI:10.13005/ojc/390628
Sudha Thotakura
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Abstract

Rare earth elements (REEs) have versatile applications in various industries and are thrown as industrial waste waters, which leads to serious environmental issues.This paper describes the adsorption efficiency of nano copper ferrite on REEs namely lanthanum and cerium in their trivalent states at room temperature and at the optimum conditions of pH, contact time, adsorbent, adsorbate dosage,temperature etc. The batch adsorption studies were conducted for the adsorption studies using ICPAES (Inductive coupled plasma atomic emission spectro photometer). In addition the data is studied for Langmuir and Freundlich models and observed that data well fitted to Langmuir monolayer adsorption. From the graph and intercept values of theoretical and experimental values, the pseudo second order kinetics are followed. Thermodynamic parameters reveal that reaction is spontaneous and endothermic. From the over all observations like fast kinetics, chemical stability, high adsorption capacity it is concluded that nano CuFe 2 O 4 has maximum efficiency for the adsorption of REEs
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使用纳米铜铁氧体高效吸附三价稀土元素:动力学、等温线和热力学
本文介绍了纳米铜铁氧体在室温以及 pH 值、接触时间、吸附剂、吸附剂用量和温度等最佳条件下对三价态稀土元素(镧和铈)的吸附效率。使用 ICPAES(电感耦合等离子体原子发射光谱光度计)进行了批量吸附研究。此外,还研究了 Langmuir 和 Freundlich 模型的数据,发现数据与 Langmuir 单层吸附非常吻合。从理论值和实验值的曲线图和截距值来看,采用的是假二阶动力学。热力学参数表明,反应是自发的、内热的。从快速动力学、化学稳定性和高吸附容量等所有观察结果可以得出结论,纳米 CuFe 2 O 4 对稀土元素的吸附效率最高。
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来源期刊
Oriental Journal Of Chemistry
Oriental Journal Of Chemistry CHEMISTRY, MULTIDISCIPLINARY-
自引率
20.00%
发文量
172
期刊介绍: Oriental Journal of Chemistry was started in 1985 with the aim to promote chemistry research. The journal consists of articles which are rigorously peer-reviewed. The journal was indexed in Emerging Science citation index in 2016. The Editorial board member consists of eminent international scientist in all fields of Chemistry. Details of each member and their contact information is mentioned in website. The journal has thorough ethics policies and uses plagiarism detection software(ithenticate) to screen each submission. The journal has recently partnered with publons as a part of making our reviews more transparent. The journal has recently incorporated PlumX for article level matrix. The journal is promoting research on all social and academic platforms mentioned in PlumX guidelines. The journal uses google maps to improve on the geographical distribution of Editorial board members as well as authors.
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