Combination of fluorescent and spin labels: a powerful method for the optimization of hydrophilic membranes for the separation of oil-in-water emulsions

Q4 Materials Science Chimica Techno Acta Pub Date : 2023-12-15 DOI:10.15826/chimtech.2023.10.4.15
Rita S. Alqubelat, Alena D. Kuznetsova, Denis O. Antonov, Maxim A. Mironov
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Abstract

A new method for assessing the quality of fibre coating based on a combination of fluorescence microscopy and electron paramagnetic resonance is presented in this work. An influence of the carboxymethylcellulose/polyvinylamine gel preparation method on the mobility of the spin label was established. The mobility of the spin label changes from 3.5 ns in the case of a polyvinylamine solution to 12.8 ns in the case of a cross-linked gel on the surface of the glass fibre. A qualitative relationship was found between the mobility of the spin label in the gel applied to the glass fibre and the rate of spreading of crude oil over its surface. This method can be used to make membranes for the separation of water-in-oil emulsions.
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荧光标签与自旋标签的结合:优化亲水膜分离水包油型乳液的有效方法
本研究提出了一种结合荧光显微镜和电子顺磁共振评估纤维涂层质量的新方法。研究确定了羧甲基纤维素/聚乙烯胺凝胶制备方法对自旋标签迁移率的影响。自旋标签的迁移率从聚乙烯胺溶液的 3.5 毫微秒变为玻璃纤维表面交联凝胶的 12.8 毫微秒。研究发现,玻璃纤维上凝胶中自旋标签的流动性与原油在其表面的扩散速度之间存在定性关系。这种方法可用于制造分离油包水型乳状液的膜。
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来源期刊
Chimica Techno Acta
Chimica Techno Acta Chemical Engineering-Chemical Engineering (all)
CiteScore
1.00
自引率
0.00%
发文量
67
审稿时长
4 weeks
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