Picropharmacolite and arsenolite from the Mareshnitsa ore occurrence, Eastern Rhodopes – new minerals for Bulgaria

S. Encheva, Nikolay Gospodinov, Denka Yanakieva, P. Petrov, Stela Atanasova-Vladimirova
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Abstract

New for Bulgaria arsenic minerals picropharmacolite and arsenolite from the Mareshnitsa ore occurrence, Eastern Rhodopes are presented. Their formation is due to the oxidation of arsenopyrite, which is abundant in the samples. The composition of the picropharmacolite from Mareshnitsa differs from the picropharmacolite from other deposits around the world. It is characterized by relatively few impurities and excess of Mg, which substitute part of Ca. This is resulting in smaller a parameter of the unit cell. The presence of these two new arsenic minerals sheds additional light on the behaviour of arsenic in the area.
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东罗多佩山脉 Mareshnitsa 矿藏中的黝帘石和砷黝帘石--保加利亚的新矿物
本报告介绍了保加利亚东罗多佩山脉 Mareshnitsa 矿区新发现的砷矿物微粉沸石和砷沸石。它们的形成是由于样品中大量的砷黄铁矿被氧化所致。来自 Mareshnitsa 的闪锌矿的成分与来自世界其他矿床的闪锌矿不同。它的特点是杂质相对较少,镁过量,替代了部分钙。这导致单位晶胞参数变小。这两种新砷矿物的出现进一步揭示了该地区砷的特性。
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