Petrography and geochemistry of Cretaceous bauxites from Jajce, Bosnia and Herzegovina

Šime Bilić, I. Peytcheva, Stoyan Georgiev, A. Hikov, Ivica Pavičić, Gordana Deljak, F. Šumanovac, Marko Holma
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Abstract

The study presents petrographic and compositional data of Late Cretaceous bauxite deposits in the area of Jajce, Bosnia and Herzegovina. Results indicate that bauxites exhibit ooidic to pisodic textures enclosed within a pelitomorfic matrix. Most of the deposits are boehmitic but in some localities, a considerable quantity of diaspore is identified. Hematite is the dominant Fe-mineral, while kaolinite, goethite and calcite are minor. The accessory minerals are represented by anatase, rutile and zircon. Al2O3 content ranges between 54.32–61.05 wt % and is negatively correlated to Fe2O3. Rare earth elements (REE) show variable concentrations, reaching up to 1353 ppm. The chondrite normalized patterns reveal negative Eu anomaly in all and positive Ce anomaly in almost all samples. Ce anomaly shows negative correlation with REE. Bauxites from the Jajce area represent valuable mineral resource with potentially valuable quantities of REE and Sc. Mineralogy and geochemical signature indicate a complex petrogenetic history.
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波斯尼亚和黑塞哥维那亚伊采白垩纪铝土矿的岩石学和地球化学研究
本研究介绍了波斯尼亚和黑塞哥维那亚伊采地区晚白垩世铝土矿床的岩石学和成分数据。研究结果表明,铝土矿呈现出鲕状至雉状纹理,并被包裹在鲕状基质中。大部分矿床为铁铝土矿,但在一些地方也发现了相当数量的透辉石。铁矿石是主要的铁矿物,而高岭石、鹅卵石和方解石则是次要矿物。附属矿物有锐钛矿、金红石和锆石。Al2O3 含量介于 54.32-61.05 wt % 之间,与 Fe2O3 呈负相关。稀土元素(REE)含量不一,最高可达 1353 ppm。软玉归一化模式显示,所有样本的 Eu 异常均为负值,几乎所有样本的 Ce 异常均为正值。铈异常与 REE 呈负相关。Jajce 地区的铝土矿是宝贵的矿产资源,可能含有大量有价值的 REE 和 Sc。矿物学和地球化学特征显示了复杂的成岩历史。
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