Geochemical study of the organic matter from the southern part of the Maritsa Iztok Basin

Z. Milakovska, Maya Stefanova, G. Vladislavov, Millena Vetseva
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Abstract

A sequence of carbonaceous mudstones interlayering three lignite seams is characterized by geochemical proxies. The core samples studied came from a borehole drilled in Trojanovo-3 Mine of Maritsa Iztok Basin. The n-alkane molecular composition is dominated by the > C29 long-chain homologues, with a strong “odd” over “even” homologue predominance. In addition to, the prevailing smooth signature of n-alkane distribution attests for one major organic matter source – land-derived higher plants. The sesqui- and di-terpenoid assemblage specifies the prevalence of Cupressaceae, Taxodiaceae, and Podocarpaceae species in the coal-forming mire. The lupane-type triterpenoids registered are a sign for Betulaceae family presence. Biomarkers for herb, macrophyte and algal/bacterial contribution are also recognizable.
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马里查-伊兹托克盆地南部有机物地球化学研究
通过地球化学代用指标,确定了三层褐煤煤层中夹杂的碳质泥岩序列的特征。所研究的岩芯样本来自于 Maritsa Iztok 盆地 Trojanovo-3 矿的钻孔。正构烷烃的分子组成以 > C29 长链同系物为主,"奇数 "同系物比 "偶数 "同系物占优势。此外,正构烷烃分布的普遍平滑特征证明了一个主要的有机物来源--源自陆地的高等植物。倍半萜和二倍半萜类化合物的组合表明,成煤沼泽中普遍生长着濯缨科、紫杉科和荚蒾科植物。所登记的羽扇豆型三萜类化合物是桦木科植物存在的标志。此外,还可以识别草本植物、大型植物和藻类/细菌的生物标记。
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