Sagarkumar Rajendrakumar Shah, N. J. Mazumdar, Ander Centeno-Pedrazo, D. Deka, N. Artioli, H. Manyar
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引用次数: 0
Abstract
Carbon dioxide is ideal for carboxylation reactions as a renewable and sustainable C1 feedstock and has significant recognition owing to its low cost, non-toxicity, and high abundance. To depreciate the environmental concentration of CO2, which causes the greenhouse gas effect, developing new catalytic protocols for organic synthesis in CO2 utilization is of great importance. This review focuses on carboxylation reactions using CO2 as a C1 feedstock to synthesize value-added functionalized carboxylic acids and their corresponding derivatives via catalytically generated allyl metal intermediates, photoredox catalysis, and electrocatalysis with a focus on recent developments and opportunities in catalyst design for carboxylation reactions. In this article, we describe recent developments in the carboxylation of C–H bonds, alkenes, and alkynes using CO2 as the C1 source for various reactions under different conditions, as well as the potential direction for the further development of CO2 utilization in organic synthesis.
期刊介绍:
Catalysts (ISSN 2073-4344) is an international open access journal of catalysts and catalyzed reactions. Catalysts publishes reviews, regular research papers (articles) and short communications. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced.