Photocatalytic Applications of SnO2 and Ag2O-Decorated SnO2 Coatings on Cement Paste

IF 3.8 3区 化学 Q2 CHEMISTRY, PHYSICAL Catalysts Pub Date : 2023-11-28 DOI:10.3390/catal13121479
Danilo da Silva Vendramini, V. G. Benatto, Alireza Mohebi Ashtiani, F. L. La Porta
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Abstract

Recently, the production of new photocatalytic materials has attracted considerable attention as a promising strategy to mitigate anthropogenic environmental degradation. In this study, cement paste composites (water/cement ratio = 0.5) were prepared using a coating based on nanoparticles of SnO2 (SnO2/cement paste) and SnO2 decorated with Ag2O (Ag2O-decorated SnO2/cement paste) for photocatalytic applications. These coatings were prepared in this study by using the hydrothermal method as the strategy. Thus, photocatalyst efficiency was evaluated through the degradation of methylene blue (MB) and methyl red (MR) as cationic and anionic dyes, respectively, and the simultaneous degradation of MB/MR (1:1 v/v) dyes. Moreover, the photocatalytic mechanism was investigated in the presence of scavengers. Notably, an increase in pH in the range of 2–6 resulted in selective degradation of the MB/MR dye mixtures. Overall, the photocatalytic performance of these materials provides a novel platform technology focused on advanced civil engineering applications, which consequently facilitates the mitigation of various environmental problems.
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水泥浆上的二氧化锡和 Ag2O-Decorated SnO2 涂层的光催化应用
近来,新型光催化材料的生产引起了人们的广泛关注,被认为是缓解人为环境退化的一种有前途的策略。本研究使用基于 SnO2 纳米颗粒的涂层(SnO2/水泥浆)和用 Ag2O 装饰的 SnO2(Ag2O-decorated SnO2/水泥浆)制备了水泥浆复合材料(水灰比 = 0.5),用于光催化应用。本研究采用水热法制备了这些涂层。因此,通过分别降解阳离子染料亚甲基蓝(MB)和阴离子染料甲基红(MR),以及同时降解 MB/MR (1:1 v/v)染料,评估了光催化剂的效率。此外,还研究了清除剂存在时的光催化机理。值得注意的是,pH 值在 2-6 范围内的增加导致了 MB/MR 染料混合物的选择性降解。总之,这些材料的光催化性能为先进的土木工程应用提供了一种新型平台技术,从而有助于缓解各种环境问题。
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来源期刊
Catalysts
Catalysts CHEMISTRY, PHYSICAL-
CiteScore
6.80
自引率
7.70%
发文量
1330
审稿时长
3 months
期刊介绍: Catalysts (ISSN 2073-4344) is an international open access journal of catalysts and catalyzed reactions. Catalysts publishes reviews, regular research papers (articles) and short communications. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced.
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