Effect of Camphor Incorporation on the Material and Antibacterial Properties of Soy Protein Isolate Films

Priya Rani, Chandrakanti Kumari, K. D. Kumar, Rakesh Kumar
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Abstract

Seeking for green alternatives to synthetic plastics, soy protein based plastics are becoming quite a popular choice. Soy protein isolate (SPI) is a plant derived protein that holds fair film forming abilities. It demonstrates evenness of film surface, decent tensile strength and interacts easily with a wide range of additives. Additives are generally added to improve the material properties and antibacterial nature of the film. In this study, we have explored the effect of camphor incorporation on the material properties and overall performance of the film. SPI based films (having 7% SPI (w/v)) were prepared by solution casting method. The concentration of camphor was varied from 0.5 to 3% w/w of 7% SPI. The films prepared by camphor addition were characterized for their transmittance, Fourier Transform Infrared (FTIR) spectroscopy and mechanical properties. The FTIR spectra confirm the incorporation of camphor as a major change in the band intensity was seen compared to neat films. However, camphor addition made the films hydrophilic and a noticeable decrease in the tensile strength was seen. The water vapour transmission rate increased upon camphor addition as compared to neat SPI films. Nevertheless, camphor- SPI film was stable as very minimum leaching occurred during the study. Unlike the neat camphor solution (1-3% w/v), the camphor modified SPI films didn’t exhibit antibacterial activity against Listeria monocytogenes and Escherichia coli. Camphor was seen to significantly increase the antioxidant properties of SPI films.
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掺入樟脑对大豆蛋白异构体薄膜的材料和抗菌性能的影响
为了寻求合成塑料的绿色替代品,基于大豆蛋白的塑料正成为一种颇受欢迎的选择。大豆分离蛋白(SPI)是一种植物提取蛋白,具有良好的成膜能力。它具有均匀的薄膜表面和良好的拉伸强度,并且很容易与各种添加剂发生作用。添加剂通常是为了改善薄膜的材料特性和抗菌性。在这项研究中,我们探讨了添加樟脑对薄膜材料特性和整体性能的影响。我们采用溶液浇铸法制备了基于 SPI 的薄膜(SPI 含量为 7%(w/v))。樟脑的浓度在 7% SPI 的 0.5% 至 3% w/w 之间变化。通过透射率、傅立叶变换红外(FTIR)光谱和机械性能对添加樟脑制备的薄膜进行了表征。傅立叶变换红外光谱证实了樟脑的加入,因为与未添加樟脑的薄膜相比,樟脑的条带强度发生了重大变化。然而,樟脑的加入使薄膜变得亲水,拉伸强度明显下降。与纯 SPI 薄膜相比,添加樟脑后水蒸气透过率增加。不过,樟脑 SPI 薄膜是稳定的,因为在研究过程中发生的沥滤非常少。与纯樟脑溶液(1-3% w/v)不同,樟脑改性 SPI 薄膜对李斯特菌和大肠杆菌没有抗菌活性。由此可见,樟脑大大提高了 SPI 薄膜的抗氧化性。
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