Experimental study on the effect of H2O and O2 on the degradation of SF6 by pulsed dielectric barrier discharge

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2023-11-16 DOI:10.1088/2058-6272/ad0d50
Yalong Li, Kun Wan, Yufei Wang, Xiaoxing Zhang, Zhaodi Yang, Mingli Fu, R. Zhuo, Dibo Wang
{"title":"Experimental study on the effect of H2O and O2 on the degradation of SF6 by pulsed dielectric barrier discharge","authors":"Yalong Li, Kun Wan, Yufei Wang, Xiaoxing Zhang, Zhaodi Yang, Mingli Fu, R. Zhuo, Dibo Wang","doi":"10.1088/2058-6272/ad0d50","DOIUrl":null,"url":null,"abstract":"SF6 has excellent insulation performance and arc extinguishing ability, and is widely used in the power industry. However, its global warming potential is about 23500 times that of CO2, and it can exist stably in the atmospheric environment, is not easy to degrade, and has great potential harm to the environment. Based on pulsed dielectric barrier discharge plasma technology, the effects of H2O and O2 on the degradation of SF6 were studied. Studies have shown that H2O and O2 can effectively promote the decomposition of SF6 and improve its degradation rate and energy efficiency. Under the action of pulse input voltage and an input frequency of 15 kV and 15 kHz respectively, when H2O has added alone, the effect of 1 % H2O is the best, and the degradation rate and energy efficiency of SF6 reach the maximum, which is 91.9 % and 8.25 g/kWh, respectively. The synergistic effect of H2O and O2 on the degradation of SF6 was similar to that of H2O. When the concentration of H2O and O2 was 1 %, the system obtained the best degradation rate and energy efficiency, which were 89.7 % and 8.05 g / kWh, respectively. At the same time, different external gases exhibit different decomposition product regulation capabilities. The addition of H2O can effectively improve the selectivity of SO2. Under the synergistic effect of H2O and O2, with the increase of O2 concentration, the degradation products gradually transformed into SO2F2.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2023-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"1089","ListUrlMain":"https://doi.org/10.1088/2058-6272/ad0d50","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

SF6 has excellent insulation performance and arc extinguishing ability, and is widely used in the power industry. However, its global warming potential is about 23500 times that of CO2, and it can exist stably in the atmospheric environment, is not easy to degrade, and has great potential harm to the environment. Based on pulsed dielectric barrier discharge plasma technology, the effects of H2O and O2 on the degradation of SF6 were studied. Studies have shown that H2O and O2 can effectively promote the decomposition of SF6 and improve its degradation rate and energy efficiency. Under the action of pulse input voltage and an input frequency of 15 kV and 15 kHz respectively, when H2O has added alone, the effect of 1 % H2O is the best, and the degradation rate and energy efficiency of SF6 reach the maximum, which is 91.9 % and 8.25 g/kWh, respectively. The synergistic effect of H2O and O2 on the degradation of SF6 was similar to that of H2O. When the concentration of H2O and O2 was 1 %, the system obtained the best degradation rate and energy efficiency, which were 89.7 % and 8.05 g / kWh, respectively. At the same time, different external gases exhibit different decomposition product regulation capabilities. The addition of H2O can effectively improve the selectivity of SO2. Under the synergistic effect of H2O and O2, with the increase of O2 concentration, the degradation products gradually transformed into SO2F2.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
脉冲介质阻挡放电中 H2O 和 O2 对 SF6 降解影响的实验研究
SF6 具有优异的绝缘性能和灭弧能力,被广泛应用于电力行业。但其全球变暖潜势约为 CO2 的 23500 倍,且能稳定存在于大气环境中,不易降解,对环境的潜在危害极大。基于脉冲介质阻挡放电等离子体技术,研究了 H2O 和 O2 对 SF6 降解的影响。研究表明,H2O 和 O2 能有效促进 SF6 的分解,提高其降解率和能效。在脉冲输入电压和输入频率分别为 15 kV 和 15 kHz 的条件下,单独添加 H2O 时,1 % H2O 的效果最好,SF6 的降解率和能效达到最大值,分别为 91.9 % 和 8.25 g/kWh。H2O 和 O2 对 SF6 降解的协同效应与 H2O 相似。当 H2O 和 O2 的浓度为 1 % 时,系统获得了最好的降解率和能效,分别为 89.7 % 和 8.05 g/kWh。同时,不同的外部气体表现出不同的分解产物调节能力。H2O 的加入能有效提高 SO2 的选择性。在 H2O 和 O2 的协同作用下,随着 O2 浓度的增加,降解产物逐渐转化为 SO2F2。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
期刊最新文献
Mentorship in academic musculoskeletal radiology: perspectives from a junior faculty member. Underlying synovial sarcoma undiagnosed for more than 20 years in a patient with regional pain: a case report. Sacrococcygeal chordoma with spontaneous regression due to a large hemorrhagic component. Associations of cumulative voriconazole dose, treatment duration, and alkaline phosphatase with voriconazole-induced periostitis. Can the presence of SLAP-5 lesions be predicted by using the critical shoulder angle in traumatic anterior shoulder instability?
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1