Comparison between Different Models for the Zn Adsorption in Some Calcareous Soils of Erbil Governate

Shayan I. Dizayee, Chnar H. Abdulrahman
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Abstract

This study was investigated to evaluate Zn adsorption using some adsorption isotherms in calcareous soils in Erbil governorate. Soil samples were taken from twelve different agricultural sites Duplicate 1 gm of soil samples were adjusted at 298° K with 50 ml of 0.01 M CaCl2.7H2O solution containing a series of Zn concentrations (0, 2, 4, 8, 16, 32, and 64) mg kg-1 using ZnSO4.7H2O. In each soil sample the amount of Zn adsorbed was calculated by using Langmuir - - pectively. While the lowest value of R2 (0.749 at 298 °K) was recorded by Harken-Juren equation. Based on the results, the effectiveness of the models in description of Zn sorption were arranged as follow: Langmuir > Freundlich > Dubinin-Radushkevich > Temkin > Harken-Juren. The lowest binding energy and maximum adsorption was recorded by Langmuir model which was regarded as the best model.
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埃尔比勒省一些石灰质土壤中锌吸附不同模型之间的比较
本研究采用一些吸附等温线来评估埃尔比勒省钙质土壤中的锌吸附情况。土壤样本取自 12 个不同的农业地点,用 50 毫升 0.01 M CaCl2.7H2O 溶液(含一系列锌浓度(0、2、4、8、16、32 和 64)毫克/千克-1)在 298° K 温度下用 ZnSO4.7H2O 调节每份 1 克的土壤样本。每个土壤样本中的锌吸附量都是通过朗缪尔公式计算得出的。而 Harken-Juren 公式的 R2 值最低(298°K 时为 0.749)。根据研究结果,各模型在描述锌吸附方面的有效性排列如下:Langmuir > Freundlich > Dubinin-Radushkevich > Temkin > Harken-Juren。朗缪尔模型的结合能最低,吸附量最大,被认为是最佳模型。
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