THE COMBINED EFFECT OF SINTERING ADDITIVES MgO AND TEOS ON THE STRUCTURE AND OPTICAL PROPERTIES OF CERAMICS YAG:Yb, Er

D. Vakalov, I. S. Chikulina, S. N. Skichuk, D. P. Bedrakov, F. Malyavin, L. V. Kozitov
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Abstract

In this work, the effect of sintering additives based on magnesium oxide (MgO) and silicon oxide (TEOS) in concentrations from 0.02 to 0.10 wt. % and 0.2 to 0.5 wt. %, respectively, was investigated on the microstructure and optical properties of ceramics of the composition Y2,82Yb0,15Er0,03Al5O12, made from powders synthesized by chemical co-deposition. The results presented in the paper showed that the introduction of a sintering additive based on MgO into a ceramic powder does not affect its phase composition, structural and morphological characteristics. It is shown that for ceramics of the composition Y2,82Yb0,15Er0,03Al5O12, the best value of the optical transmission coefficient was achieved at a vacuum sintering temperature of 1800 °C and a concentration of sintering additives of 0.06 wt. % MgO and 0.3 wt. % TEOS. It is shown that the sintering mechanism of ceramics Y2,82Yb0,15Er0,03Al5O12 depends on the ratio of sintering additives MgO and TEOS.
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氧化镁和 TEOS 掺杂剂对 YAG:Yb,Er 陶瓷结构和光学特性的综合影响
在这项工作中,研究了基于氧化镁(MgO)和氧化硅(TEOS)的烧结添加剂(浓度分别为 0.02 至 0.10 wt. % 和 0.2 至 0.5 wt. %)对由化学共沉积法合成的 Y2,82Yb0,15Er0,03Al5O12 陶瓷粉末的微观结构和光学特性的影响。论文的研究结果表明,在陶瓷粉末中加入基于氧化镁的烧结添加剂不会影响其相组成、结构和形态特征。结果表明,对于成分为 Y2,82Yb0,15Er0,03Al5O12 的陶瓷,在真空烧结温度为 1800 ℃、烧结添加剂浓度为 0.06 wt. % MgO 和 0.3 wt. % TEOS 时,光传输系数达到了最佳值。研究表明,Y2,82Yb0,15Er0,03Al5O12 陶瓷的烧结机理取决于烧结添加剂氧化镁和 TEOS 的比例。
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