SYNTHESIS AND INVESTIGATION OF PROPERTIES OF MULLITE-CORUNDUM CERAMICS AS A COMPONENT OF CERAMIC COMPOSITE MATERIALS

Abstract

The paper studies the conditions for synthesis of mullite-corundum ceramics obtained on the basis of Al2O3 and SiO2. The composition of mullite-corundum ceramics with an Al2O3 content < 80 wt.% has been determined, which ensures the best thermomechanical compatibility with molybdenum. The possibility of obtaining a composite material based on a mullite-corundum matrix and molybdenum, as well as its use as a barrier layer at the interface of Мo–Si-containing ceramics, has been confirmed. It is established that use of barrier layer significantly reduces the likelihood of thermal stresses in the interface of the two phases. It is shown that there is a need to refine the technological parameters of the preparation of the powder Al2O3–SiO2 mixture to increase the thermochemical compatibility of molybdenum with mullite-corundum ceramics.