Green synthesis of AgNPs from leaves extract of Saliva Sclarea, their characterization, antibacterial activity, and catalytic reduction ability

Shahab Khan, Ihsan Ullah, Hamayun Khan, Faizan Ur Rahman, M. Rahman, Muhammad Asim Saleem, Shoaib Nazir, Arshad Ali, Arif Ullah
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Abstract

Abstract Several technologies are employed for the synthesis of silver nanoparticles, each synthesis technique has advantages and disadvantages, and the best technique relies on the application at hand, the required qualities of the nanoparticles, and the size of the product. But in this article green synthesis were followed. In this research, AgNPs were synthesized using Salvia Sclarea leaf extract in green synthetic routes. The synthesized nanoparticles were examined using UV–vis spectroscopy, powder XRD, SEM, and FT-IR. Here three different type of silver nanoparticles were biosynthesized, AgNPs-1, AgNPs-2, and AgNPs-3 (where composition of AgNO3 and extract were 6:1, 10:1 and 14:1 respectively). The catalytic ability of AgNPs 1–3 was determine in the reduction of nitro-compounds into corresponding amines, where AgNPs-2 was found efficient reductive catalyst. Moreover, antibacterial activities were checked against both gram-positive (Bacillus Suntilis) and gram-negative bacteria (Klebsiella pneumoniae). Upon increasing Ag contents antibacterial activities were found in increasing mode. Which open new era of knowledge for further consideration.
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用丹参叶提取物绿色合成 AgNPs 及其表征、抗菌活性和催化还原能力
摘要 目前有几种合成银纳米粒子的技术,每种合成技术都有优缺点,最佳技术取决于手头的应用、对纳米粒子质量的要求以及产品的尺寸。但本文采用的是绿色合成技术。本研究采用丹参叶提取物的绿色合成路线合成了 AgNPs。使用紫外-可见光谱、粉末 XRD、扫描电镜和傅立叶变换红外光谱对合成的纳米粒子进行了检测。生物合成了三种不同类型的银纳米粒子:AgNPs-1、AgNPs-2 和 AgNPs-3(其中 AgNO3 与提取物的比例分别为 6:1、10:1 和 14:1)。测定了 AgNPs 1-3 在将硝基化合物还原成相应胺类化合物过程中的催化能力,发现 AgNPs-2 是高效的还原催化剂。此外,还检测了 AgNPs 对革兰氏阳性菌(孙蒂利杆菌)和革兰氏阴性菌(肺炎克雷伯菌)的抗菌活性。随着 Ag 含量的增加,抗菌活性也随之增加。这为进一步研究开辟了新的知识领域。
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