Effect of bead mill dispermat system with specific surfactants on organic pigments

Nilesh Prakash Badgujar, Ravindra D. Kulkarni, S. Sonawane, Hansraj V. Patil, Karuppiah Nagaraj, Matar Alshalwi
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Abstract

Abstract The study demonstrates the effective application of high-speed dispersion and bead mill dispermat systems in dispersing organic pigments, specifically phthalocyanine blue and green, in water with positive results. Particle size analysis reveals that formulations prepared using a bead mill with the selective surfactants such as Tween-80, SLS, Cocosulphosuccinate (CSPS) and Oleyl sulphosuccinate (OSPS) which exhibits a narrower range of particle size distribution compared to those prepared using high-speed dispersion (HSD). Phthalocyanine blue pigment concentrate formulation, the bead mill preparation using Tween-80 and CSPS surfactants resulted in a higher viscosity and color strength compared to HSD. In addition, the phthalocyanine green pigment concentrate formulation prepared using a bead mill with SLS surfactant showed higher color strength than the formulation prepared using HSD with SLS surfactant. Moreover, the comparative study reported the Nano CaCO3 pigment concentrate formulation prepared using a bead mill with SLS surfactant displayed a narrow range of particle size distribution ranging from 0.31 to 0.56 nm, with an average particle size of 0.435 nm, compared to the formulation prepared using HSD. All these findings suggested bead mill dispermat system with specific surfactants can produce pigment dispersions with a narrower particle size distribution, higher color strength, and better viscosity compared to HSD which demonstrating its potential as a more efficient and effective method for pigment dispersion.
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含有特定表面活性剂的珠磨机分散体系对有机颜料的影响
摘要 该研究证明了高速分散系统和珠磨机分散系统在水中分散有机颜料(特别是酞菁蓝和酞菁绿)方面的有效应用,并取得了积极成果。粒度分析表明,使用珠磨机和选择性表面活性剂(如吐温-80、SLS、椰油基磺基琥珀酸酯(CSPS)和油基磺基琥珀酸酯(OSPS))制备的配方与使用高速分散剂(HSD)制备的配方相比,粒度分布范围更窄。与 HSD 相比,使用吐温-80 和 CSPS 表面活性剂的珠磨法制备的酞菁蓝浓缩颜料配方具有更高的粘度和着色力。此外,使用珠磨机和 SLS 表面活性剂制备的酞菁绿颜料浓缩配方比使用 HSD 和 SLS 表面活性剂制备的配方显示出更高的着色力。此外,比较研究还发现,与使用 HSD 制备的配方相比,使用珠磨机和 SLS 表面活性剂制备的纳米 CaCO3 颜料浓缩配方的粒度分布范围较窄,从 0.31 纳米到 0.56 纳米不等,平均粒度为 0.435 纳米。所有这些研究结果表明,与 HSD 相比,使用特定表面活性剂的珠磨机分散体系能制备出粒径分布更窄、着色力更强、粘度更好的颜料分散体,这表明它有潜力成为一种更高效、更有效的颜料分散方法。
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