Porous pathways: Exploring the future of conducting polymers

IF 1.7 4区 化学 Bulletin of the Korean Chemical Society Pub Date : 2024-01-11 DOI:10.1002/bkcs.12814
Hyeonseong Ham, Geunhong Sim, Woongsik Choi, Moon Jeong Park
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Abstract

Conducting polymers (CPs) possess the intrinsic attractive properties of conventional polymers, coupled with unique electronic characteristics reminiscent of metals or semiconductors. Nanostructured CPs have recently gained significant interest for their distinct advantages over bulk counterparts. They demonstrate potential applications in energy storage devices, sensors, and catalysts, attributed to their large surface areas and shortened charge transport paths. A crucial structural aspect in this context includes introducing porous morphologies into CPs, and enhancing their functionality through interconnected channels. In this review, various synthetic methods of nanostructured CPs are introduced, emphasizing two-dimensional (2D) configurations. The primary objective is to achieve high-performance devices with highly organized stacking of conjugated backbones. Particular attention is placed on integrating 2D structures and porous morphologies into CPs through ice-assisted methods and interfacial synthesis. The review also highlights successful applications of porous 2D CPs in practical devices and explores insights into future developments in the porous CPs field.

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多孔途径:探索导电聚合物的未来
导电聚合物(CPs)具有传统聚合物固有的诱人特性,同时还具有类似金属或半导体的独特电子特性。最近,纳米结构导电聚合物因其相对于块状导电聚合物的独特优势而备受关注。由于具有较大的表面积和较短的电荷传输路径,它们在储能设备、传感器和催化剂方面具有潜在的应用前景。在此背景下,一个关键的结构方面包括将多孔形态引入氯化石蜡,并通过相互连接的通道增强其功能。在本综述中,介绍了纳米结构氯化石蜡的各种合成方法,重点是二维(2D)构型。其主要目的是通过共轭骨架的高度有序堆叠实现高性能器件。特别关注的是通过冰辅助方法和界面合成将二维结构和多孔形态整合到氯化石蜡中。综述还重点介绍了多孔二维共轭骨架在实际器件中的成功应用,并探讨了多孔共轭骨架领域的未来发展。
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来源期刊
Bulletin of the Korean Chemical Society
Bulletin of the Korean Chemical Society Chemistry-General Chemistry
自引率
23.50%
发文量
182
期刊介绍: The Bulletin of the Korean Chemical Society is an official research journal of the Korean Chemical Society. It was founded in 1980 and reaches out to the chemical community worldwide. It is strictly peer-reviewed and welcomes Accounts, Communications, Articles, and Notes written in English. The scope of the journal covers all major areas of chemistry: analytical chemistry, electrochemistry, industrial chemistry, inorganic chemistry, life-science chemistry, macromolecular chemistry, organic synthesis, non-synthetic organic chemistry, physical chemistry, and materials chemistry.
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