Possibility of Processing the Kaolin Clays from the Suvorovskoe Deposit with Coagulant Extraction

IF 0.4 Q4 METALLURGY & METALLURGICAL ENGINEERING Russian Metallurgy (Metally) Pub Date : 2024-01-18 DOI:10.1134/s0036029523090021
B. G. Balmaev, A. S. Tuzhilin, T. N. Vetchinkina, Yu. V. Zablotskaya
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Abstract

The mineral and chemical compositions of the kaolin clay from the Suvorovskoe deposit are studied by X-ray diffraction and inductively coupled plasma atomic emission spectrometry. The conditions of the thermal calcination and decomposition of the kaolin clay with sulfuric and hydrochloric acids are optimized: the calcination temperature and time are 650–700°C and 60–90 min, respectively. The degree of extraction of Al2O3 from the calcined clay to sulfuric acid solutions is 92–94%, and that to hydrochloric acid solutions is 76–78%. The influence of different flocculants on the separation of liquid and solid phases is studied. The use of polyacrylamide is shown to increase the filtration rate by a factor of 1.5–2. The coagulation properties of aluminum sulfate and hydroxochlorides, namely, oxidizability, chromaticity, and concentrations of aluminum and iron in the treated water, are studied. The tested coagulants can efficiently be applied for the treatment of drinking and sewage waters at low and high temperatures in a wide pH range of the waters to be treated.

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用混凝剂萃取法加工苏沃洛夫斯科矿藏高岭土的可能性
摘要 通过 X 射线衍射和电感耦合等离子体原子发射光谱法研究了苏沃洛夫斯科矿床高岭土的矿物和化学成分。用硫酸和盐酸对高岭土进行热煅烧和分解的条件进行了优化:煅烧温度和时间分别为 650-700°C 和 60-90 分钟。煅烧后的粘土对硫酸溶液的 Al2O3 萃取率为 92-94%,对盐酸溶液的萃取率为 76-78%。研究了不同絮凝剂对液相和固相分离的影响。结果表明,使用聚丙烯酰胺可将过滤率提高 1.5-2 倍。研究了硫酸铝和羟基氯化物的混凝特性,即氧化性、色度以及处理后水中铝和铁的浓度。所测试的混凝剂可在低温和高温条件下,在待处理水的广泛 pH 值范围内,有效地用于饮用水和污水的处理。
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Russian Metallurgy (Metally)
Russian Metallurgy (Metally) METALLURGY & METALLURGICAL ENGINEERING-
CiteScore
0.70
自引率
25.00%
发文量
140
期刊介绍: Russian Metallurgy (Metally)  publishes results of original experimental and theoretical research in the form of reviews and regular articles devoted to topical problems of metallurgy, physical metallurgy, and treatment of ferrous, nonferrous, rare, and other metals and alloys, intermetallic compounds, and metallic composite materials. The journal focuses on physicochemical properties of metallurgical materials (ores, slags, matters, and melts of metals and alloys); physicochemical processes (thermodynamics and kinetics of pyrometallurgical, hydrometallurgical, electrochemical, and other processes); theoretical metallurgy; metal forming; thermoplastic and thermochemical treatment; computation and experimental determination of phase diagrams and thermokinetic diagrams; mechanisms and kinetics of phase transitions in metallic materials; relations between the chemical composition, phase and structural states of materials and their physicochemical and service properties; interaction between metallic materials and external media; and effects of radiation on these materials.
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