Preparation of robust superhydrophobic surface on PET substrate using Box-Behnken design and facile sanding method with PTFE powder

IF 4.7 Q2 MATERIALS SCIENCE, BIOMATERIALS ACS Applied Bio Materials Pub Date : 2024-01-19 DOI:10.1088/1361-6439/ad208a
Xin Wang, Tao Wang, Jie Sheng, Ziting Wang, Weizhi Yang, Meng Li, Liping Shi
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Abstract

Superhydrophobic surfaces have attracted increasing interests due to their excellent features, while achieving facile preparation of superhydrophobic surface with good mechanical stability is still a challenging work. In this paper, we prepared a superhydrophobic surface by sanding polytetrafluoroethylene powder directly onto the surface of a polyethylene terephthalate (PET) film by means of a simple sanding method with sandpaper. The fabrication parameters were firstly optimized using response surface methodology. Surface morphology and chemical composition of the fabricated surface were characterized by SEM, FTIR and XPS. The mechanical performance of the superhydrophobic PET surfaces was evaluated by tape peeling test, and potential applications of this surface in self-cleaning and anti-icing were finally carried out. The results showed that the water contact angle (WCA) up to 153.5° and sliding angle (SA) less than ~3° on PET surface could be prepared under the optimum conditions, and its superhydrophobicity of surfaces was attributed to the synergistically effect of low surface energy and surface roughness. The fabricated superhydrophobic surfaces also exhibited good resistance to abrasion, and they have great potential for application in the fields of self-cleaning and anti-icing.
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利用盒式贝肯设计和简易打磨法与聚四氟乙烯粉末在 PET 基材上制备坚固的超疏水表面
超疏水表面因其优异的特性引起了人们越来越多的关注,但如何便捷地制备出具有良好机械稳定性的超疏水表面仍是一项具有挑战性的工作。本文采用简单的砂纸打磨法,将聚四氟乙烯粉末直接打磨到聚对苯二甲酸乙二醇酯(PET)薄膜表面,制备出了超疏水表面。首先利用响应面方法对制造参数进行了优化。利用扫描电镜、傅立叶变换红外光谱和 XPS 对制备表面的形貌和化学成分进行了表征。通过胶带剥离测试评估了超疏水 PET 表面的机械性能,并最终确定了该表面在自清洁和防结冰方面的潜在应用。结果表明,在最佳条件下,PET 表面的水接触角(WCA)可达 153.5°,滑动角(SA)小于 ~3°,其表面超疏水性归因于低表面能和表面粗糙度的协同作用。制备的超疏水表面还表现出良好的耐磨性,在自清洁和防结冰领域具有巨大的应用潜力。
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来源期刊
ACS Applied Bio Materials
ACS Applied Bio Materials Chemistry-Chemistry (all)
CiteScore
9.40
自引率
2.10%
发文量
464
期刊介绍: ACS Applied Bio Materials is an interdisciplinary journal publishing original research covering all aspects of biomaterials and biointerfaces including and beyond the traditional biosensing, biomedical and therapeutic applications. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrates knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important bio applications. The journal is specifically interested in work that addresses the relationship between structure and function and assesses the stability and degradation of materials under relevant environmental and biological conditions.
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