Stress Corrosion Cracking of High-Strength Ni-Base Alloys in PWR Primary Water Containing KOH vs. LiOH

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-01-16 DOI:10.5006/4460
Z. Zhai, Ferdinan Cintron-Colon, Ryan A. Bouffioux, M. Toloczko
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Abstract

The stress corrosion cracking behavior of high-strength Ni-base Alloy X-750 and Alloy 718 has been investigated to assess the effect of replacing LiOH with KOH as the pH moderator in pressurized water reactor (PWR) primary circuit coolant. The SCC initiation behavior of X-750 was evaluated by multi-tensile specimen constant load test in either LiOH- or KOH- containing PWR primary water. The SCC growth behavior of X-750 and Alloy 718 was evaluated on compact tension specimens with on-the-fly changes between LiOH- and KOH-containing water in three different PWR primary water chemistries. Direct current potential drop technique was used for in-situ monitoring of crack initiation time and crack extension in SCC initiation and propagation tests, respectively. The results suggest no significant effect of KOH vs. LiOH on the SCC initiation or propagation of the tested materials.
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高强度镍基合金在含 KOH 与 LiOH 的压水堆原水中的应力腐蚀裂纹
对高强度镍基合金 X-750 和合金 718 的应力腐蚀开裂行为进行了研究,以评估在压水堆(PWR)一回路冷却剂中用 KOH 取代 LiOH 作为 pH 值调节剂的效果。在含有 LiOH 或 KOH 的压水堆一回路水中,通过多拉伸试样恒载试验对 X-750 的 SCC 引发行为进行了评估。在三种不同的压水堆一次水化学成分中,在含 LiOH 和 KOH 的水之间快速变化的紧凑拉伸试样上,对 X-750 和合金 718 的 SCC 生长行为进行了评估。在 SCC 起始和扩展试验中,分别使用了直流电位降技术对裂纹起始时间和裂纹扩展进行原位监测。结果表明,KOH 与 LiOH 对测试材料的 SCC 起始或扩展没有明显影响。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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