Investigation of TiO2 replacement alternatives for water-based paints using styrene butyl acrylate

IF 1.3 4区 材料科学 Q3 CHEMISTRY, APPLIED Pigment & Resin Technology Pub Date : 2024-01-25 DOI:10.1108/prt-12-2023-0110
Seda Aygül, Serkan Yılmazsönmez, Arzu Soyalp, Ayse Aytac
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Abstract

Purpose

Titanium dioxide (TiO2) has high opacity, high brightness and whiteness, owing to its high refractive index value. It is mainly used in the coating industry and continuous efforts have been made to replace some of the TiO2 in paint with new pigments. This study aims to replace part of TiO2 pigment with various percentages of BaSO4, CaCO3 and kaolin in styrene butyl acrylate-based paint formulations, without changing the properties of paints using only titanium dioxide.

Design/methodology/approach

To determine the optimum use rate of new pigment mixing, opacity, gloss, scrub resistance and weather resistance properties have been investigated in the water-based paint formulation. The morphological properties of these samples were examined by scanning electron microscopy analysis.

Findings

In the total color change (ΔE) measurements, it was observed that the sample coded 85Ti/15Ba produced extremely similar results to the situation when TiO2 was used alone. It was seen that the best results were obtained when 85Ti/15Ba was used instead of TiO2.

Originality/value

Comparison research on the impact of replacing TiO2 with BaSO4, CaCO3 and kaolin on the performance characteristics of water-based styrene butyl acrylate-based paint formulations has not been done in the literature, according to the literature search.

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使用丙烯酸苯乙烯丁酯的水基涂料中二氧化钛替代品的研究
用途二氧化钛(TiO2)因其折射率高而具有高不透明度、高亮度和白度。它主要用于涂料工业,人们一直在努力用新颜料替代涂料中的部分 TiO2。本研究旨在用不同比例的 BaSO4、CaCO3 和高岭土取代苯乙烯-丙烯酸丁酯基涂料配方中的部分 TiO2 颜料,同时不改变仅使用二氧化钛的涂料的特性。通过扫描电子显微镜分析检查了这些样品的形态特性。在总颜色变化(ΔE)测量中发现,编码为 85Ti/15Ba 的样品产生的结果与单独使用 TiO2 时的结果极为相似。原创性/价值根据文献检索,关于用 BaSO4、CaCO3 和高岭土替代 TiO2 对水性苯乙烯-丙烯酸丁酯基涂料配方的性能特征的影响的比较研究在文献中尚未出现。
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来源期刊
Pigment & Resin Technology
Pigment & Resin Technology 工程技术-材料科学:膜
CiteScore
2.80
自引率
21.40%
发文量
91
审稿时长
>12 weeks
期刊介绍: The journal looks at developments in: ■Adhesives and sealants ■Curing and coatings ■Wood coatings and preservatives ■Environmentally compliant coating systems and pigments ■Inks for food packaging ■Manufacturing machinery - reactors, mills mixing and dispersing equipment, pumps ■Packaging, labeling and storage ■Plus topical features and news on materials, coatings, industry people, conferences, books and so on ■Raw materials such as pigments, solvents, resins and chemicals ■Testing equipment and procedures
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