Stabilization of Swellable Aluminosilicate Suspensions

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-01-26 DOI:10.1134/S1061933X2360094X
K. A. Ovchinnikov, E. V. Podlesnova, F. E. Safarov, A. T. Akhmetov, A. V. Fakhreeva, E. I. Gusarova, N. A. Sergeeva, A.G. Telin
{"title":"Stabilization of Swellable Aluminosilicate Suspensions","authors":"K. A. Ovchinnikov,&nbsp;E. V. Podlesnova,&nbsp;F. E. Safarov,&nbsp;A. T. Akhmetov,&nbsp;A. V. Fakhreeva,&nbsp;E. I. Gusarova,&nbsp;N. A. Sergeeva,&nbsp;A.G. Telin","doi":"10.1134/S1061933X2360094X","DOIUrl":null,"url":null,"abstract":"<p>The goal of this study is to increase the energy efficiency of pipeline hydraulic transport of water-swellable aluminosilicate dispersions. A model commercial suspension, the filler of which is a complex mixture of aluminosilicates, has been used to develop an approach that makes it possible to improve the technological properties of such suspensions. Modification of the suspensions consists in adding organic and inorganic inhibitors of swelling of dispersed phase particles, as well as nonionic surfactants. The influence of the additives leads to a decrease in the yield stress and an increase in sedimentation stability of the heterogeneous systems. It has been shown that the use of the complex modifying additive prevents the particles of the model suspension from agglomeration and provides it with sedimentation stability at temperatures up to 70°C, which is important for the technical process in which the suspension is intended to be used. Technically, the research is of an applied nature. A well-known approach to modifying suspensions is used, which consists in combating the aggregation of dispersed phase particles and blocking ion exchange between them and the dispersion medium. The performed set of rheological shear and oscillation tests and the study of the sedimentation stability of the suspensions in the presence of various modifying additives have resulted in optimizing their composition. The practical result of the work is the successful hydrotransport of the suspension in which the content of the dispersed phase is 50% higher than that in the unmodified suspension, thus increasing the energy efficiency of the process.</p>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-01-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1061933X2360094X","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

The goal of this study is to increase the energy efficiency of pipeline hydraulic transport of water-swellable aluminosilicate dispersions. A model commercial suspension, the filler of which is a complex mixture of aluminosilicates, has been used to develop an approach that makes it possible to improve the technological properties of such suspensions. Modification of the suspensions consists in adding organic and inorganic inhibitors of swelling of dispersed phase particles, as well as nonionic surfactants. The influence of the additives leads to a decrease in the yield stress and an increase in sedimentation stability of the heterogeneous systems. It has been shown that the use of the complex modifying additive prevents the particles of the model suspension from agglomeration and provides it with sedimentation stability at temperatures up to 70°C, which is important for the technical process in which the suspension is intended to be used. Technically, the research is of an applied nature. A well-known approach to modifying suspensions is used, which consists in combating the aggregation of dispersed phase particles and blocking ion exchange between them and the dispersion medium. The performed set of rheological shear and oscillation tests and the study of the sedimentation stability of the suspensions in the presence of various modifying additives have resulted in optimizing their composition. The practical result of the work is the successful hydrotransport of the suspension in which the content of the dispersed phase is 50% higher than that in the unmodified suspension, thus increasing the energy efficiency of the process.

Abstract Image

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
稳定可膨胀硅酸铝悬浮液
摘要 本研究的目标是提高水膨胀硅酸铝分散体管道水力运输的能效。我们使用了一种商业悬浮液模型(其填料是一种复杂的铝硅酸盐混合物)来开发一种方法,从而有可能改善这种悬浮液的技术特性。悬浮液的改良包括添加有机和无机分散相颗粒膨胀抑制剂以及非离子表面活性剂。在添加剂的影响下,异质体系的屈服应力降低,沉降稳定性提高。研究表明,使用复合改性添加剂可以防止模型悬浮液的颗粒团聚,并使其在高达 70°C 的温度下具有沉降稳定性,这对于悬浮液的使用技术过程非常重要。从技术上讲,这项研究具有应用性质。我们采用了一种众所周知的方法来改良悬浮液,即防止分散相颗粒聚集并阻止它们与分散介质之间的离子交换。通过流变剪切和振荡试验,以及对悬浮液在各种改性添加剂作用下的沉降稳定性的研究,对悬浮液的成分进行了优化。这项工作的实际成果是成功实现了悬浮液的水力传输,其中分散相的含量比未改性悬浮液高出 50%,从而提高了工艺的能效。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
期刊最新文献
Management of Cholesteatoma: Hearing Rehabilitation. Congenital Cholesteatoma. Evaluation of Cholesteatoma. Management of Cholesteatoma: Extension Beyond Middle Ear/Mastoid. Recidivism and Recurrence.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1