Interception of layered LP-N and HLP-N at ambient conditions by confined template

Dong-Xue Wang, Jing Fu, Yi Li, Zhen Yao, Shuang Liu, Bing-Bing Liu
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Abstract

We proposed a feasible strategy of intercepting the LP-N and HLP-N at ambient conditions by using the confinement templates. The stable mechanism of confined LP-N and HLP-N at ambient conditions is revealed, namely the synergistic effect of charge transfer and vdW confinement effect. The influence rule of interlayer spacing on the stability of LP-N is revealed. Most importantly, the nitrogen content and energy density of recoverable LP-N@graphene (70.59%, 8.15 kJ/g), LP-N@hBN (70.59%, 7.96 kJ/g), HLP-N@graphene (68.97%, 9.31 kJ/g) and HLP-N@h-BN (69.57%, 8.05 kJ/g) refresh the new record for the confinement polynitrogen system.
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封闭模板在环境条件下拦截分层 LP-N 和 HLP-N
我们提出了利用禁锢模板在环境条件下拦截 LP-N 和 HLP-N 的可行策略。揭示了环境条件下禁锢 LP-N 和 HLP-N 的稳定机制,即电荷转移和 vdW 禁锢效应的协同效应。揭示了层间距对 LP-N 稳定性的影响规律。最重要的是,可回收的 LP-N@石墨烯(70.59%,8.15 kJ/g)、LP-N@hBN(70.59%,7.96 kJ/g)、HLP-N@石墨烯(68.97%,9.31 kJ/g)和 HLP-N@h-BN(69.57%,8.05 kJ/g)的氮含量和能量密度刷新了约束多氮体系的新纪录。
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