Microwave Absorption Properties of Ceramics Based on BiFeO3 Modified with Ho

Solids Pub Date : 2024-01-17 DOI:10.3390/solids5010005
P. Astafev, Konstantin Andryushin, A. Pavelko, Alexander Lerer, Yakov Reizenkind, Ekaterina Glazunova, L. Shilkina, Inna Andryushina, Alexandr Nagaenko, Larisa Reznichenko
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Abstract

Ceramic samples of Bi1−xHoxFeO3, where x = 0.00–0.50, with a modifier concentration variation step ∆x = 0.05–0.10, were prepared by a two-step solid-phase synthesis followed by sintering using conventional ceramic technology. X-ray phase analysis showed that all the solid solutions studied were formed in the presence of impurities. With increasing Ho concentration, a non-monotonic shift in all loss maxima towards the low-frequency region is observed, as well as an increase in their half-width. An increase in the external temperature leads to a monotonic shift in the absorption maxima towards the low-frequency region, which enables the necessary control of the microwave parameters in the X band. A conclusion has been drawn on the feasibility of using the data obtained in the design of new functional materials based on BiFeO3, as well as devices with thermally controlled frequency.
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基于用 Ho 改性的 BiFeO3 陶瓷的微波吸收特性
通过两步固相合成法制备了 Bi1-xHoxFeO3 陶瓷样品(其中 x = 0.00-0.50,改性剂浓度变化步骤 ∆x = 0.05-0.10),然后使用传统陶瓷技术进行烧结。X 射线相分析表明,所研究的所有固溶体都是在存在杂质的情况下形成的。随着 Ho 浓度的增加,所有损耗最大值都向低频区域发生了非单调移动,其半宽度也有所增加。外部温度的升高导致吸收最大值向低频区单调移动,从而实现了对 X 波段微波参数的必要控制。最后得出的结论是,利用所获得的数据设计基于 BiFeO3 的新型功能材料以及具有热控频率的设备是可行的。
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