Vanadian–Chromian Spinels (Sludyanka Metamorphic Complex, South Baikal Area). Magnesian Spinel

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-01-16 DOI:10.2113/rgg20234659
L. Reznitsky, E. Sklyarov, I. G. Barash
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Abstract

—The paper presents data on two groups of magnesian Cr–V spinel occurring as rock-forming minerals in various types of Cr–V bearing rocks of the Sludyanka metamorphic complex (South Baikal area, Siberia, Russia): (i) low-Al magnesiochromite–magnesiocoulsonite spinels and (ii) Al spinels varying from V-bearing aluminous magnesiochromite and Al–Cr coulsonite to spinel proper with minor contents of Cr and V, and with complex zoning patterns. Spinels in the Sludyanka rocks are also present as iron-magnesian accessories, among which high-Cr varieties are compositionally similar to mantle-derived spinel from igneous rocks and to inclusions in diamonds. Comparison of formation conditions for mantle spinels in igneous lithologies and spinel phases in metamorphic rocks shows that their mineral chemistry is mainly controlled by the bulk composition of the igneous and sedimentary protoliths, respectively. Detrital spinel may be a false indicator poorly applicable to paleogeodynamic reconstructions and diamond potential evaluation.
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Vanadian-Chromian尖晶石(南贝加尔湖地区 Sludyanka 变质岩群)。镁质尖晶石
-本文介绍了在斯卢迪扬卡变质岩群(俄罗斯西伯利亚南贝加尔湖地区)各类含Cr-V的岩石中作为成岩矿物出现的两组镁质Cr-V尖晶石的数据:(i) 低铝镁铬铁矿-镁镁荃铁尖晶石;(ii) 铝尖晶石,从含V的铝镁铬铁矿和铝铬荃铁矿到含少量Cr和V的尖晶石不等,且具有复杂的分带模式。斯鲁迪扬卡岩石中的尖晶石还以铁镁质附件的形式存在,其中高铬品种的成分与火成岩中的地幔尖晶石和钻石中的包裹体相似。对火成岩岩性中的地幔尖晶石和变质岩中的尖晶石相的形成条件进行比较后发现,它们的矿物化学成分主要分别受火成岩和沉积岩原岩体成分的控制。碎屑尖晶石可能是一个错误的指标,不适用于古地球动力学重建和金刚石潜力评估。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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