{"title":"Vanadian–Chromian Spinels (Sludyanka Metamorphic Complex, South Baikal Area). Magnesian Spinel","authors":"L. Reznitsky, E. Sklyarov, I. G. Barash","doi":"10.2113/rgg20234659","DOIUrl":null,"url":null,"abstract":"\n —The paper presents data on two groups of magnesian Cr–V spinel occurring as rock-forming minerals in various types of Cr–V bearing rocks of the Sludyanka metamorphic complex (South Baikal area, Siberia, Russia): (i) low-Al magnesiochromite–magnesiocoulsonite spinels and (ii) Al spinels varying from V-bearing aluminous magnesiochromite and Al–Cr coulsonite to spinel proper with minor contents of Cr and V, and with complex zoning patterns. Spinels in the Sludyanka rocks are also present as iron-magnesian accessories, among which high-Cr varieties are compositionally similar to mantle-derived spinel from igneous rocks and to inclusions in diamonds. Comparison of formation conditions for mantle spinels in igneous lithologies and spinel phases in metamorphic rocks shows that their mineral chemistry is mainly controlled by the bulk composition of the igneous and sedimentary protoliths, respectively. Detrital spinel may be a false indicator poorly applicable to paleogeodynamic reconstructions and diamond potential evaluation.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":" 23","pages":""},"PeriodicalIF":17.7000,"publicationDate":"2024-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"89","ListUrlMain":"https://doi.org/10.2113/rgg20234659","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
—The paper presents data on two groups of magnesian Cr–V spinel occurring as rock-forming minerals in various types of Cr–V bearing rocks of the Sludyanka metamorphic complex (South Baikal area, Siberia, Russia): (i) low-Al magnesiochromite–magnesiocoulsonite spinels and (ii) Al spinels varying from V-bearing aluminous magnesiochromite and Al–Cr coulsonite to spinel proper with minor contents of Cr and V, and with complex zoning patterns. Spinels in the Sludyanka rocks are also present as iron-magnesian accessories, among which high-Cr varieties are compositionally similar to mantle-derived spinel from igneous rocks and to inclusions in diamonds. Comparison of formation conditions for mantle spinels in igneous lithologies and spinel phases in metamorphic rocks shows that their mineral chemistry is mainly controlled by the bulk composition of the igneous and sedimentary protoliths, respectively. Detrital spinel may be a false indicator poorly applicable to paleogeodynamic reconstructions and diamond potential evaluation.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.