Palladium-free multicomponent high temperature shape memory alloys

IF 5.7 1区 工程技术 Q1 ENGINEERING, MULTIDISCIPLINARY International Journal of Engineering Science Pub Date : 2024-02-01 DOI:10.1016/j.ijengsci.2024.104027
N. Resnina , S. Belyaev , A. Bazlov , I. Ponikarova , A. Sibirev , A. Ivanov , R. Bikbaev , I. Strochko
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Abstract

One of the challenges is the design of the relatively cheap Pd-free multicomponent high-temperature shape memory alloys. This paper presents the route for solving this problem by an increasing the Hf concentration in Ti–Hf–Zr–Ni–Cu–Co alloys. It was found that an increase in the Hf concentration from 23 to 32 at.% increased the transformation temperatures: Af changed from 90 °C to 220 °C, Ms varied from 35 °C to 172 °C, while the hysteresis was constant and equal to 45–48 °C. Further increase in the Hf concentration increased the Af temperature by 20 °C but hardly affected the Ms temperatures. Recoverable strain variation was studied on cooling under stress (in torsion mode) and heating without stress. Strain jumps were observed on γ(T) curves which were attributed to a large martensite plate appeared on cooling or disappeared on heating within large grain, which was accompanied by the abrupt strain variation. An increase in the Hf concentration decreased recoverable strain, as well as the strain up to failure. This was due to an increase in the size and volume of the brittle [Ti]2[Ni] and [Hf]2[Ni] precipitates. A maximum recoverable strain of 5 % was found in the alloy with 23 at.% of Hf, whereas the recoverable strain did not exceed 1 % in the alloys with 32 and 38 at.% of Hf.

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无钯多组分高温形状记忆合金
挑战之一是设计相对便宜的不含 Pd 的多组分高温形状记忆合金。本文介绍了通过增加 Ti-Hf-Zr-Ni-Cu-Co 合金中的 Hf 浓度来解决这一问题的途径。研究发现,将 Hf 浓度从 23% 提高到 32% 会提高转化温度:Af从90 °C变为220 °C,Ms从35 °C变为172 °C,而滞后不变,等于45-48 °C。进一步增加 Hf 浓度会使 Af 温度升高 20 °C,但几乎不会影响 Ms 温度。研究了应力冷却(扭转模式)和无应力加热时的可恢复应变变化。在 γ(T) 曲线上观察到了应变跳跃,这是由于大晶粒内的大马氏体板在冷却时出现或在加热时消失,同时伴随着突然的应变变化。Hf 浓度的增加降低了可恢复应变以及直至破坏的应变。这是由于脆性[Ti]2[Ni]和[Hf]2[Ni]沉淀的尺寸和体积增大所致。Hf 含量为 23% 的合金的最大可恢复应变为 5%,而 Hf 含量为 32% 和 38% 的合金的可恢复应变不超过 1%。
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来源期刊
International Journal of Engineering Science
International Journal of Engineering Science 工程技术-工程:综合
CiteScore
11.80
自引率
16.70%
发文量
86
审稿时长
45 days
期刊介绍: The International Journal of Engineering Science is not limited to a specific aspect of science and engineering but is instead devoted to a wide range of subfields in the engineering sciences. While it encourages a broad spectrum of contribution in the engineering sciences, its core interest lies in issues concerning material modeling and response. Articles of interdisciplinary nature are particularly welcome. The primary goal of the new editors is to maintain high quality of publications. There will be a commitment to expediting the time taken for the publication of the papers. The articles that are sent for reviews will have names of the authors deleted with a view towards enhancing the objectivity and fairness of the review process. Articles that are devoted to the purely mathematical aspects without a discussion of the physical implications of the results or the consideration of specific examples are discouraged. Articles concerning material science should not be limited merely to a description and recording of observations but should contain theoretical or quantitative discussion of the results.
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