Study on water migration and microstructure of unsaturated expansive clays

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-02-02 DOI:10.1144/qjegh2023-067
Qiuyan Liu, Mingwu Wang
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Abstract

Because of the characteristics of water-swelling and drying shrinkage, the mechanical performances of expansive clay in semi-arid areas deteriorate with the change in humidity and temperature. So investigating the moisture migration in expansive clays is of great significance. Herein, scanning electron microscopy test and water migration tests of unsaturated soil were carried out to address the water variation law and microscopic mechanism in the unsaturated expansive clay. It is found that small and medium-sized pores (2-10μm) are dominated, and these pores are conducive to the rise of water in the soil. The soil with high water content exhibits a flocculent structure, characterized by a small fractal dimension and a high relative hydraulic conductivity. Conversely, the soil with low water content displays a dispersed structure, featuring a large fractal dimension and a low relative hydraulic conductivity. The water migration tests under constant temperature(5, 20, and 40°C) and variable temperature (15-25°C) show that the migration amount at 5°C and 20°C was about 25%-40%, 40%-60% of that at 40°C, respectively. The amount of water migration under constant temperature was obviously lower than that under variable temperature. The research results have provided technical support for effective control of soil change.
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非饱和膨胀性粘土的水分迁移和微观结构研究
由于水膨胀和干燥收缩的特性,半干旱地区膨胀性粘土的力学性能会随着湿度和温度的变化而恶化。因此,研究膨胀性粘土中的水分迁移具有重要意义。本文针对非饱和膨胀性粘土的水分变化规律和微观机理,进行了扫描电镜试验和非饱和土水分迁移试验。研究发现,土壤中以中小型孔隙(2-10μm)为主,这些孔隙有利于土壤中水分的上升。含水量高的土壤呈现絮状结构,其特点是分形维数小,相对导水性高。相反,含水量低的土壤则呈现分散结构,分形维数大,相对导水率低。恒温(5、20 和 40°C)和变温(15-25°C)条件下的水分迁移试验表明,5°C 和 20°C 时的迁移量分别约为 40°C 时的 25%-40%、40%-60%。恒温条件下的水迁移量明显低于变温条件下的迁移量。研究成果为有效控制土壤变化提供了技术支持。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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