Prototropic Tautomerism of o-Oxyazomethines. Crystal Structure of (E)-1-(((Pyridin-3-ylmethyl)iminio)methyl)naphthalen-2-olate

IF 0.6 4区 材料科学 Q4 CRYSTALLOGRAPHY Crystallography Reports Pub Date : 2024-02-06 DOI:10.1134/s1063774523600382
V. S. Sergienko, V. L. Abramenko, M. D. Surazhskaya, A. V. Churakov
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Abstract

(Е)-1-(((Pyridin-3-ylmethyl)iminio)methyl)naphthalen-2-olate (H2L1) was synthesized and characterized by IR spectroscopy and single-crystal X-ray diffraction analysis. In the structure of H2L1, the bicyclic naphthalene ring system С10Н6 and the pyridine ring (Ру) are linked by the zigzag three-unit chain HC–N–CH2. The structure of the H2L1 molecule was compared with the known structures of the compounds containing two six-membered rings (two Ph rings or Ph and Ру rings) linked by zigzag n-unit chains (n = 3, 4, 6, 7).

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邻氧氮杂环丁烷的原位同分异构。(E)-1-(((吡啶-3-基甲基)亚氨基)甲基)萘-2-醇的晶体结构
摘要合成了(Е)-1-(((吡啶-3-基甲基)亚氨基)甲基)萘-2-醇(H2L1),并通过红外光谱和单晶 X 射线衍射分析对其进行了表征。在 H2L1 的结构中,双环萘环系统 С10Н6 和吡啶环(Ру)通过 HC-N-CH2 人字形三单位链连接。我们将 H2L1 分子的结构与已知的含有两个六元环(两个 Ph 环或 Ph 环和 Ру环)的化合物的结构进行了比较,这些化合物由之字形 n 单元链连接(n = 3、4、6、7)。
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来源期刊
Crystallography Reports
Crystallography Reports 化学-晶体学
CiteScore
1.10
自引率
28.60%
发文量
96
审稿时长
4-8 weeks
期刊介绍: Crystallography Reports is a journal that publishes original articles short communications, and reviews on various aspects of crystallography: diffraction and scattering of X-rays, electrons, and neutrons, determination of crystal structure of inorganic and organic substances, including proteins and other biological substances; UV-VIS and IR spectroscopy; growth, imperfect structure and physical properties of crystals; thin films, liquid crystals, nanomaterials, partially disordered systems, and the methods of studies.
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