Rare Earth Elements in the Aqueous Phase of Mud Volcanoes of the Kerch-Taman Region

IF 0.3 Q4 GEOLOGY Moscow University Geology Bulletin Pub Date : 2024-02-07 DOI:10.3103/s0145875223060054
G. A. Chelnokov, N. A. Kharitonova, V. Yu. Lavrushin, A. S. Aydarkozhina, Guodong Zheng
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Abstract

This work presents original data on the contents and distribution of major and rare earth elements in the waters from 26 mud volcanoes within the Kerch–Taman region. In terms of the chemical composition, the studied mud volcanic waters are the Na–Cl and Na–HCO3–Cl types. However, the Cl/Br, Na/Cl, and Y/ Ho ratios indicate three main genetic groups of volcanoes. It was found that the contents of the rare earth elements in the aqueous phase of mud volcanoes are low (fractions of μg/L) and are distinguished by negative cerium anomalies and positive europium and holmium anomalies. The highest REE concentrations are observed in the mud volcanoes located within the oldest Cretaceous sediments in the area of fault influence. As the distance from the Mesozoic source ΣREE dramatically decreases, it was revealed that the free CO2 content in the aqueous phase regulates the REE content in waters and the cerium and europium anomalies.

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刻赤-塔曼地区泥火山水相中的稀土元素
摘要 这项工作提供了有关刻赤-塔曼地区 26 座泥火山水体中主要元素和稀土元素的含量和分布的原始数据。从化学成分来看,所研究的泥火山水属于 Na-Cl 和 Na-HCO3-Cl 类型。然而,Cl/Br、Na/Cl 和 Y/ Ho 比率表明火山有三大基因组。研究发现,泥火山水相中的稀土元素含量较低(微克/升的分数),其特征是铈异常为负值,铕和钬异常为正值。在断层影响区最古老的白垩纪沉积物中的泥火山,观察到的 REE 浓度最高。随着与中生代ΣREE源的距离急剧减小,发现水相中的游离二氧化碳含量调节着水中的REE含量以及铈和铕的异常。
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来源期刊
CiteScore
0.60
自引率
25.00%
发文量
43
期刊介绍: Moscow University Geology Bulletin  is the journal that mainly publishes scientific articles, short reports of graduate students, and reviews. Publications made by the members of the Faculty of Geology of the Moscow State University and their collaborators are published. Publications encompass all branches of geology.
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