Synthesis of TiO2/ZnO Nanocomposites by the Electrochemical Method and Their Application in Dye-Sensitized Solar Cells (DSSCs)

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-02-01 DOI:10.22146/ijc.87071
Aqeel Mahdi Alduhaidahawi, A. A. Ahmed
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Abstract

Various standard methods have previously been used for the synthesis of nanoparticles that produce unhealthy waste. They are also considered unsafe and expensive methods. An alternative technology is needed to synthesize nanoparticles that consume less energy and are more environmentally friendly. In this research, a TiO2/ZnO nanocomposite has been synthesized, which was produced with efficient energy and no environmental pollution using an easy and fast method (electrochemical). Additionally, dye-sensitized solar cells (DSSCs) have been fabricated from TiO2/ZnO nanocomposite which was synthesized by a new green method and pigments (methylene blue as a chemical dye and chlorophyll as a natural dye). These DSSCs were characterized by their high ability to absorb ultraviolet energy, where the efficiency of energy conversion η of ITO-TiO2/ZnO were approximately 2.08, and 3.04% with chlorophyll and methylene blue, respectively, showing that η of ITO-TiO2/ZnO with methylene blue was the best.
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用电化学方法合成 TiO2/ZnO 纳米复合材料及其在染料敏化太阳能电池 (DSSC) 中的应用
以前曾使用过各种标准方法合成纳米粒子,但这些方法会产生不健康的废物。这些方法也被认为是不安全和昂贵的方法。我们需要一种能耗更低、更环保的替代技术来合成纳米粒子。在这项研究中,我们合成了一种 TiO2/ZnO 纳米复合材料,它是用一种简便、快速的方法(电化学法)生产出来的,具有高效能源和无环境污染的特点。此外,还利用新型绿色方法合成的 TiO2/ZnO 纳米复合材料和颜料(化学染料亚甲基蓝和天然染料叶绿素)制作了染料敏化太阳能电池(DSSC)。这些 DSSC 的特点是吸收紫外线能量的能力很强,其中含有叶绿素和亚甲基蓝的 ITO-TiO2/ZnO 的能量转换效率η 分别约为 2.08% 和 3.04%,表明含有亚甲基蓝的 ITO-TiO2/ZnO 的能量转换效率η 最好。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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