Effect of Individual Alloying Addition on the Microstructure and Creep Behavior of Squeeze Cast AZ91 Magnesium Alloy

Hitesh Patil, Abhijit Ghosh, Hemant Borkar
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Abstract

The microstructure of AZ91 (Mg-Al) alloy is comprised of α-Mg and β-Mg17Al12 massive phase. The lower melting point associated with the β-Mg17Al12 phase results in poor creep resistance of the alloy. In the present study, the AZ91 alloy with the addition of calcium (Ca, 1wt%) and cerium (Ce, 1wt%) is cast, and their effect on the microstructure and creep behavior of AZ91 alloy have been investigated. Thermally stable phases such as Al2Ca and Al11Ce3 are introduced in the AZ91 alloy through the addition of Ca and Ce elements. Energy dispersive spectroscopy (EDS) and x-ray diffraction analysis confirmed the presence of these intermetallic phases in the microstructure. Tensile creep tests on the as-cast samples were performed at 175°C temperature under 50 MPa stress. The study shows that the creep resistance of AZ91 alloy is greatly improved with the presence of Al2Ca and Al11Ce3 intermetallic phases because of their better thermal stability than β-Mg17Al12.
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单个合金添加物对挤压铸造 AZ91 镁合金微观结构和蠕变行为的影响
AZ91 (镁-铝)合金的微观结构由 α-Mg 和 β-Mg17Al12 块状相组成。β-Mg17Al12相的熔点较低,导致合金的抗蠕变性较差。本研究铸造了添加钙(Ca,1wt%)和铈(Ce,1wt%)的 AZ91 合金,并研究了它们对 AZ91 合金微观结构和蠕变行为的影响。通过添加钙和铈元素,在 AZ91 合金中引入了 Al2Ca 和 Al11Ce3 等热稳定相。能量色散光谱(EDS)和 X 射线衍射分析证实了微观结构中存在这些金属间相。在 175°C 温度和 50 兆帕应力条件下,对铸件样品进行了拉伸蠕变试验。研究结果表明,由于 Al2Ca 和 Al11Ce3 金属间相的热稳定性比 β-Mg17Al12 更好,因此它们的存在大大提高了 AZ91 合金的抗蠕变性。
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