Modified basalt material reinforced organic coatings: A review

Guangguang Xiang , Hongpeng Zheng , Bing Lin , Yingying Wang , Hailong Zhang , Dan Wang , Junlei Tang , Li Liu , Fuhui Wang
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Abstract

Natural basalt can be processed into rod-like basalt fibers (BFs) and flake-like basalt scales (BSs) through high-temperature melting, forming and other processes. BFs and BSs have great application prospects in the field of organic coatings. BFs possess a regular rod-like structure and excellent mechanical properties, which are mainly used to enhance the mechanical properties of organic coatings. BSs possess a relatively irregular flake-like structure, which can form “maze” effects and layered structures to enhance corrosion resistance of organic coatings. However, basalt materials have poor compatibility, adhesion, and dispersion in organic resins due to their chemical inertness, resulting in a weak basalt-resin interface. Basalt-resin interface is an important parameter that determines the service performance of basalt composite coatings. Therefore, it is necessary to improve basalt-resin interface through corresponding strategies, such as chemical etching, chemical grafting and plasma treatment. Firstly, the surface modification strategies for improving basalt-matrix interface were summarized in this paper. Secondly, we discussed the effects of BFs and BSs on corrosion resistance of organic coatings and corrosion protection mechanism of composite coatings. Finally, we reviewed the research progress of modified basalt materials reinforced organic coatings.

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改性玄武岩材料增强有机涂料:综述
天然玄武岩可通过高温熔化、成型等工艺加工成棒状玄武岩纤维(BFs)和片状玄武岩鳞片(BSs)。玄武岩纤维和玄武岩鳞片在有机涂料领域具有广阔的应用前景。BFs 具有规则的棒状结构和优异的机械性能,主要用于增强有机涂层的机械性能。玄武岩具有相对不规则的片状结构,可形成 "迷宫 "效应和层状结构,从而增强有机涂层的耐腐蚀性。然而,玄武岩材料由于其化学惰性,在有机树脂中的相容性、粘附性和分散性较差,导致玄武岩-树脂界面不牢固。玄武岩-树脂界面是决定玄武岩复合涂料使用性能的一个重要参数。因此,有必要通过化学蚀刻、化学接枝和等离子处理等相应策略来改善玄武岩-树脂界面。本文首先总结了改善玄武岩-基体界面的表面改性策略。其次,讨论了 BFs 和 BSs 对有机涂层耐腐蚀性的影响以及复合涂层的腐蚀防护机理。最后,综述了改性玄武岩材料增强有机涂层的研究进展。
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