The extraction process of nanocellulose from organic waste and incorporating it into biopolymers for mechanical property enhancement

Lamia Afrin Ratry, Md. Bazlul Mobin Siddique
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Abstract

Nanocellulose possesses excellent properties such as an elastic modulus of 220 GPa, Young’s modulus of 10- 150 GPa, low density of around 1.6 g/cm3, and high thermal stability. To enhance mechanical flexibility, nanocellulose can strengthen the bio-polymers. This research project aims to review the extraction methods and the characterization of the nanocellulose extracted from organic waste materials such as banana peel, pineapple leaf fiber, crown, corncob, palm oil, etc., focusing on the possibility of adding the nanocellulose to enhance the properties such as tensile strength, young’s modulus, water vapor permeability of the biopolymers. Chemical extraction methods like alkaline treatment, bleaching treatment, sulfuric and formic acid hydrolysis, TEMPO-mediated oxidation, and mechanical extraction methods such as ball milling, ultrasonication, high-pressure homogenization, and grinding have been studied. The results obtained from all the characterization techniques have been tabulated. From the results tabulation, the length of cellulose nanocrystal and cellulose nanofiber is 100-350 nm and 350 nm and above, respectively. The hydrolysis time and the types of acid used will affect the yield and aspect ratio; the acid concentration will also affect the degradation temperature. Mechanical treatment results in a higher yield of the nanocellulose, but mechanical treatment is not economically solvent due to the heavy use of power. Considering that nanocellulose extracted via chemo-mechanical treatment has outstanding characteristics that can potentially improve the mechanical properties when incorporated into the biopolymers.
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从有机废弃物中提取纳米纤维素并将其融入生物聚合物以提高机械性能的过程
纳米纤维素具有优异的特性,如弹性模量为 220 GPa,杨氏模量为 10-150 GPa,密度低至约 1.6 g/cm3,热稳定性高。为增强机械柔韧性,纳米纤维素可强化生物聚合物。本研究项目旨在综述从香蕉皮、菠萝叶纤维、树冠、玉米芯、棕榈油等有机废料中提取纳米纤维素的提取方法和表征,重点研究添加纳米纤维素以增强生物聚合物的拉伸强度、杨氏模量、水蒸气渗透性等性能的可能性。研究了碱处理、漂白处理、硫酸和甲酸水解、TEMPO 介导的氧化等化学提取方法,以及球磨、超声波、高压均质化和研磨等机械提取方法。所有表征技术的结果均已列表。从结果表中可以看出,纤维素纳米晶和纤维素纳米纤维的长度分别为 100-350 nm 和 350 nm 及以上。水解时间和所用酸的种类会影响产率和长宽比,酸的浓度也会影响降解温度。机械处理可获得更高的纳米纤维素产率,但由于耗电量大,机械处理不是经济的溶剂。考虑到通过化学机械处理提取的纳米纤维素具有出色的特性,在加入到生物聚合物中后有可能改善其机械性能。
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