{"title":"Investigation of the doubly excited 1Po resonance series in C4+ ion","authors":"Stéphane Laulan, Marc-André Albert, Samira Barmaki","doi":"10.1016/j.elspec.2024.147429","DOIUrl":null,"url":null,"abstract":"<div><p>We investigate in the present paper the doubly excited <span><math><mrow><msup><mrow></mrow><mrow><mn>1</mn></mrow></msup><msup><mrow><mi>P</mi></mrow><mrow><mi>o</mi></mrow></msup></mrow></math></span> states in the C<span><math><msup><mrow></mrow><mrow><mn>4</mn><mo>+</mo></mrow></msup></math></span> ion. We report highly accurate results of their energy positions in the energy spectrum, their lifetimes and the x-ray photon energies required to populate them and observe their autoionization. The results were obtained by using our B-spline based spectral approach combined with the complex rotation method that has proven its effectiveness in the detection of the doubly excited states in the O<span><math><msup><mrow></mrow><mrow><mn>6</mn><mo>+</mo></mrow></msup></math></span> <span>[1]</span> and Li<span><math><msup><mrow></mrow><mrow><mo>+</mo></mrow></msup></math></span> <span>[2]</span> ions. We also report in the paper the first results on the characterization and identification of the states that share similar angular correlation pattern, which allows their classification into distinct resonance series.</p></div>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0368204824000124","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
We investigate in the present paper the doubly excited states in the C ion. We report highly accurate results of their energy positions in the energy spectrum, their lifetimes and the x-ray photon energies required to populate them and observe their autoionization. The results were obtained by using our B-spline based spectral approach combined with the complex rotation method that has proven its effectiveness in the detection of the doubly excited states in the O [1] and Li [2] ions. We also report in the paper the first results on the characterization and identification of the states that share similar angular correlation pattern, which allows their classification into distinct resonance series.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.