Investigation of the doubly excited 1Po resonance series in C4+ ion

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-01-01 DOI:10.1016/j.elspec.2024.147429
Stéphane Laulan, Marc-André Albert, Samira Barmaki
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Abstract

We investigate in the present paper the doubly excited 1Po states in the C4+ ion. We report highly accurate results of their energy positions in the energy spectrum, their lifetimes and the x-ray photon energies required to populate them and observe their autoionization. The results were obtained by using our B-spline based spectral approach combined with the complex rotation method that has proven its effectiveness in the detection of the doubly excited states in the O6+ [1] and Li+ [2] ions. We also report in the paper the first results on the characterization and identification of the states that share similar angular correlation pattern, which allows their classification into distinct resonance series.

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研究 C4+ 离子中的双激发 1Po 共振系列
我们在本文中研究了 C4+ 离子中的双激发 1Po 态。我们报告了它们在能谱中的能量位置、寿命以及填充它们和观察它们自电离所需的 X 射线光子能量的高精度结果。这些结果是通过使用我们基于 B-样条曲线的光谱方法与复旋转方法相结合获得的,该方法已被证明在探测 O6+ [1] 和 Li+ [2] 离子的双激发态方面非常有效。我们还在论文中首次报告了对具有相似角相关模式的态进行特征描述和识别的结果,这样就可以将它们划分为不同的共振系列。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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