The Effects of Shear Parameters on the Stability of Emulsion Explosive Matrices

IF 1.4 4区 化学 Q4 CHEMISTRY, PHYSICAL Colloid Journal Pub Date : 2024-02-20 DOI:10.1134/s1061933x23600872
Jianmin Zhou, Yongsheng Jia, Yingkang Yao, Xianqi Xie, Mingsheng Zhao
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Abstract

This work demonstrated the criterion of shear stability of emulsion explosive matrices (EEM), combined with rheology test, interfacial tension test, droplet size test and the crystallization test of emulsion explosive matrices. The shear stability of emulsion explosive matrices was defined as the characteristic refinement time of the droplet size decrease in emulsification process. The constitutive relationship between the characteristic refinement time and droplet size of inner phase droplets was proposed by theoretical analysis and experiments on the emulsification process of emulsion explosive matrices. By analyzing the relationship between rheological properties and characteristic refinement time of emulsion explosive matrices, the relationship model between Bingham coefficient and dimensionless coefficient was established to characterize the shear stability of emulsion explosive matrices. The effects of shear strength, shear time and shear shape on the stability of emulsion explosive matrices were studied. In addition, there exists a critical value to quantitatively characterize the shear stability of emulsion explosive matrices.

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剪切参数对乳化炸药基质稳定性的影响
摘要 本研究结合乳化炸药基质的流变学试验、界面张力试验、液滴粒度试验和结晶试验,论证了乳化炸药基质剪切稳定性的标准。乳化炸药基质的剪切稳定性定义为乳化过程中液滴粒径减小的特征细化时间。通过对乳化炸药基质乳化过程的理论分析和实验,提出了特征细化时间与内相液滴尺寸之间的构成关系。通过分析乳化炸药基质流变特性与特征细化时间的关系,建立了宾汉系数与无量纲系数的关系模型,表征了乳化炸药基质的剪切稳定性。研究了剪切强度、剪切时间和剪切形状对乳化炸药基质稳定性的影响。此外,还提出了定量表征乳化炸药基质剪切稳定性的临界值。
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来源期刊
Colloid Journal
Colloid Journal 化学-物理化学
CiteScore
2.20
自引率
18.20%
发文量
36
审稿时长
6-12 weeks
期刊介绍: Colloid Journal (Kolloidnyi Zhurnal) is the only journal in Russia that publishes the results of research in the area of chemical science dealing with the disperse state of matter and surface phenomena in disperse systems. The journal covers experimental and theoretical works on a great variety of colloid and surface phenomena: the structure and properties of interfaces; adsorption phenomena and structure of adsorption layers of surfactants; capillary phenomena; wetting films; wetting and spreading; and detergency. The formation of colloid systems, their molecular-kinetic and optical properties, surface forces, interaction of colloidal particles, stabilization, and criteria of stability loss of different disperse systems (lyosols and aerosols, suspensions, emulsions, foams, and micellar systems) are also topics of the journal. Colloid Journal also includes the phenomena of electro- and diffusiophoresis, electro- and thermoosmosis, and capillary and reverse osmosis, i.e., phenomena dealing with the existence of diffusion layers of molecules and ions in the vicinity of the interface.
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