{"title":"Phase-Transfer Catalysis for Electrochemical Chlorination and Nitration of Arenes","authors":"Yingdong Duan, Dr. Prof. Sanzhong Luo","doi":"10.1002/anie.202319206","DOIUrl":null,"url":null,"abstract":"<p>A biphasic anodic oxidation method for aromatic halogenation process was developed, where aqueous metal salts were directly used as halogen source. Ammonium salts serve as both electrolytes and phase transfer catalysis to facilitate anion transport and oxidative transformation. This design allows for chlorination or nitration of multiple types of arenes using NaCl or KNO<sub>2</sub>.</p>","PeriodicalId":125,"journal":{"name":"Angewandte Chemie International Edition","volume":null,"pages":null},"PeriodicalIF":16.1000,"publicationDate":"2024-02-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie International Edition","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/anie.202319206","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
A biphasic anodic oxidation method for aromatic halogenation process was developed, where aqueous metal salts were directly used as halogen source. Ammonium salts serve as both electrolytes and phase transfer catalysis to facilitate anion transport and oxidative transformation. This design allows for chlorination or nitration of multiple types of arenes using NaCl or KNO2.
期刊介绍：
Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.
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