Daniil A. Bardonov, Darina I. Nasyrova, Dmitrii M. Roitershtein, Konstantin A. Lyssenko, Mikhail E. Minyaev
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引用次数: 0
Abstract
Crystal structures of mononuclear cyclopentadienyl-anthracenide complexes [(1,3-Ph2C5H3)Lu(C14H10)(THF)2]•THF (1a), [(1,2,4-Ph3C5H2)Lu(C14H10)(THF)2]•0.17hexane•1.53THF (2a), [(1,2,4-Ph3C5H2)Lu(C14H10)(THF)2]•3C6D6 (2b), [(1,2,4-Ph3C5H2)Y(C14H10)(THF)2] •0.23hexane•1.37THF (3a), and [(1,2,4-Ph3C5H2)Lu(2,6-tBu2C14H8)(THF)2]•0.5THF (4a) have been studied. Complexes exhibit a structural rigidity of the (η5-C5)Ln(η2-C14)(O)2 crystallographic node. Electronic and steric effects are discussed. The cyclopentadienyl-anthracenide complexes are able to activate C = C bonds without a co-catalyst, using ethylene polymerization as an example.
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Structural Chemistry is an international forum for the publication of peer-reviewed original research papers that cover the condensed and gaseous states of matter and involve numerous techniques for the determination of structure and energetics, their results, and the conclusions derived from these studies. The journal overcomes the unnatural separation in the current literature among the areas of structure determination, energetics, and applications, as well as builds a bridge to other chemical disciplines. Ist comprehensive coverage encompasses broad discussion of results, observation of relationships among various properties, and the description and application of structure and energy information in all domains of chemistry.
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