Increasing the Lifetime of Water Transportation Vehicles by Using Multifunctional Composites with a Polymer Matrix, Ultradisperse Diamond, and Discrete Fibrous Filler
A. V. Buketov, Yu. M. Shulga, I. P. Fesenko, O. M. Bezbakh, O. A. Pastukh
{"title":"Increasing the Lifetime of Water Transportation Vehicles by Using Multifunctional Composites with a Polymer Matrix, Ultradisperse Diamond, and Discrete Fibrous Filler","authors":"A. V. Buketov, Yu. M. Shulga, I. P. Fesenko, O. M. Bezbakh, O. A. Pastukh","doi":"10.3103/S1063457624010027","DOIUrl":null,"url":null,"abstract":"<p>Epoxy resin polymer composites with improved mechanical and thermophysical properties have been developed. To improve the material characteristics, an ultradisperse diamond and a multifunctional discrete fibrous (polyester–viscose–elastane) filler are added to the epoxy oligomer. The following properties of the composites are studied: hardness, residual stress, and thermal coefficients of linear expansion. It is established that the optimal concentration is in the range of <i>q</i> = 0.02–0.03 wt % relative to 100 wt % of the epoxy matrix for the multifunctional discrete fibrous filler and 0.05 wt % per 100 wt % of the epoxy matrix for the ultradisperse diamond. The models of formation of the structure of composites during the cross-linking process are proposed. They imply the presence of a polymer in the composites, an additional filler in the form of fibers, and a third structure in the form of external surface layers that are formed around the fibers in the polymerization process. The models illustrate the formation of the structure of composites at the micro-, meso-, and macroscopic levels.</p>","PeriodicalId":670,"journal":{"name":"Journal of Superhard Materials","volume":"46 1","pages":"40 - 54"},"PeriodicalIF":1.2000,"publicationDate":"2024-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Superhard Materials","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.3103/S1063457624010027","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Epoxy resin polymer composites with improved mechanical and thermophysical properties have been developed. To improve the material characteristics, an ultradisperse diamond and a multifunctional discrete fibrous (polyester–viscose–elastane) filler are added to the epoxy oligomer. The following properties of the composites are studied: hardness, residual stress, and thermal coefficients of linear expansion. It is established that the optimal concentration is in the range of q = 0.02–0.03 wt % relative to 100 wt % of the epoxy matrix for the multifunctional discrete fibrous filler and 0.05 wt % per 100 wt % of the epoxy matrix for the ultradisperse diamond. The models of formation of the structure of composites during the cross-linking process are proposed. They imply the presence of a polymer in the composites, an additional filler in the form of fibers, and a third structure in the form of external surface layers that are formed around the fibers in the polymerization process. The models illustrate the formation of the structure of composites at the micro-, meso-, and macroscopic levels.
期刊介绍:
Journal of Superhard Materials presents up-to-date results of basic and applied research on production, properties, and applications of superhard materials and related tools. It publishes the results of fundamental research on physicochemical processes of forming and growth of single-crystal, polycrystalline, and dispersed materials, diamond and diamond-like films; developments of methods for spontaneous and controlled synthesis of superhard materials and methods for static, explosive and epitaxial synthesis. The focus of the journal is large single crystals of synthetic diamonds; elite grinding powders and micron powders of synthetic diamonds and cubic boron nitride; polycrystalline and composite superhard materials based on diamond and cubic boron nitride; diamond and carbide tools for highly efficient metal-working, boring, stone-working, coal mining and geological exploration; articles of ceramic; polishing pastes for high-precision optics; precision lathes for diamond turning; technologies of precise machining of metals, glass, and ceramics. The journal covers all fundamental and technological aspects of synthesis, characterization, properties, devices and applications of these materials. The journal welcomes manuscripts from all countries in the English language.