Increasing the Lifetime of Water Transportation Vehicles by Using Multifunctional Composites with a Polymer Matrix, Ultradisperse Diamond, and Discrete Fibrous Filler

IF 1.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Superhard Materials Pub Date : 2024-03-04 DOI:10.3103/S1063457624010027
A. V. Buketov, Yu. M. Shulga, I. P. Fesenko, O. M. Bezbakh, O. A. Pastukh
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Abstract

Epoxy resin polymer composites with improved mechanical and thermophysical properties have been developed. To improve the material characteristics, an ultradisperse diamond and a multifunctional discrete fibrous (polyester–viscose–elastane) filler are added to the epoxy oligomer. The following properties of the composites are studied: hardness, residual stress, and thermal coefficients of linear expansion. It is established that the optimal concentration is in the range of q = 0.02–0.03 wt % relative to 100 wt % of the epoxy matrix for the multifunctional discrete fibrous filler and 0.05 wt % per 100 wt % of the epoxy matrix for the ultradisperse diamond. The models of formation of the structure of composites during the cross-linking process are proposed. They imply the presence of a polymer in the composites, an additional filler in the form of fibers, and a third structure in the form of external surface layers that are formed around the fibers in the polymerization process. The models illustrate the formation of the structure of composites at the micro-, meso-, and macroscopic levels.

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通过使用含有聚合物基体、超分散金刚石和离散纤维填料的多功能复合材料提高水上运输车辆的使用寿命
摘要 开发出了具有更好机械性能和热物理性能的环氧树脂聚合物复合材料。为改善材料特性,在环氧树脂低聚物中添加了超分散金刚石和多功能离散纤维(聚酯-粘胶-弹性体)填料。对复合材料的以下性能进行了研究:硬度、残余应力和线性热膨胀系数。结果表明,相对于 100 重量百分比的环氧基体,多功能离散纤维填料的最佳浓度范围为 q = 0.02-0.03 重量百分比,超分散金刚石的最佳浓度范围为每 100 重量百分比的环氧基体 0.05 重量百分比。提出了在交联过程中形成复合材料结构的模型。这意味着复合材料中存在聚合物、纤维形式的附加填料以及聚合过程中在纤维周围形成的外表面层形式的第三种结构。这些模型说明了复合材料结构在微观、中观和宏观层面的形成。
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来源期刊
Journal of Superhard Materials
Journal of Superhard Materials MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
1.80
自引率
66.70%
发文量
26
审稿时长
2 months
期刊介绍: Journal of Superhard Materials presents up-to-date results of basic and applied research on production, properties, and applications of superhard materials and related tools. It publishes the results of fundamental research on physicochemical processes of forming and growth of single-crystal, polycrystalline, and dispersed materials, diamond and diamond-like films; developments of methods for spontaneous and controlled synthesis of superhard materials and methods for static, explosive and epitaxial synthesis. The focus of the journal is large single crystals of synthetic diamonds; elite grinding powders and micron powders of synthetic diamonds and cubic boron nitride; polycrystalline and composite superhard materials based on diamond and cubic boron nitride; diamond and carbide tools for highly efficient metal-working, boring, stone-working, coal mining and geological exploration; articles of ceramic; polishing pastes for high-precision optics; precision lathes for diamond turning; technologies of precise machining of metals, glass, and ceramics. The journal covers all fundamental and technological aspects of synthesis, characterization, properties, devices and applications of these materials. The journal welcomes manuscripts from all countries in the English language.
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