Deposition and Localization of Polishing Powder Wear Nanoparticles on the Processed Surface of Polymeric Optical Materials

IF 1.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Superhard Materials Pub Date : 2024-03-04 DOI:10.3103/S1063457624010040
Yu. D. Filatov, V. I. Sidorko, S. V. Kovalev, A. Y. Boyarintsev, V. A. Kovalev, O. Y. Yurchyshyn
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Abstract

The investigation revealed patterns in the formation and localization of deposits of polishing powder wear nanoparticles on the processed surface during the polishing of polymeric materials using disperse systems of micro- and nanopowders. The total scattering cross section of polishing powder wear nanoparticles on sludge nanoparticles increases nonlinearly with the movement of particles, extremally depends on the product of spectral separation for dielectric constant separation between the processed material, polishing powder, and the disperse system, and exponentially increases with the resonator detuning. When polystyrene is polished using cerium dioxide micropowder, deposition on the processed surface is most likely to occur, with the maximum value of the total scattering cross section of polishing powder wear nanoparticles on sludge nanoparticles being at 49.7 Mb. Experimental data indicate that the localization of deposits with polishing powder wear nanoparticles on the processed surface occurs according to the distribution function of the total scattering cross section of polishing powder wear nanoparticles on sludge nanoparticles across circular zones, which aligns well with experimental results, within 12.5%. The experimentally determined average thickness of the deposit fragments of polishing powder wear nanoparticles, forming complete or partial coverage of the component surface, ranges from 1.1 to 1.5 µm.

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抛光粉磨损纳米颗粒在聚合物光学材料加工表面的沉积和定位
摘要 研究揭示了在使用微粉和纳米粉体的分散体系对聚合物材料进行抛光时,抛光粉磨损纳米颗粒在被加工表面的沉积物的形成和定位模式。抛光粉磨损纳米颗粒在污泥纳米颗粒上的总散射截面随颗粒的移动而非线性增加,极度依赖于被加工材料、抛光粉和分散系统之间介电常数分离的光谱分离乘积,并随谐振器失谐而指数增加。当使用二氧化铈微粉抛光聚苯乙烯时,最有可能在加工表面发生沉积,抛光粉磨损纳米粒子在污泥纳米粒子上的总散射截面的最大值为 49.7 Mb。实验数据表明,根据抛光粉磨损纳米颗粒在污泥纳米颗粒上的总散射截面在圆形区域内的分布函数,抛光粉磨损纳米颗粒在加工表面上的沉积物会发生定位,这与实验结果非常吻合,在 12.5%以内。实验确定的抛光粉纳米颗粒沉积碎片的平均厚度为 1.1 至 1.5 µm,完全或部分覆盖部件表面。
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来源期刊
Journal of Superhard Materials
Journal of Superhard Materials MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
1.80
自引率
66.70%
发文量
26
审稿时长
2 months
期刊介绍: Journal of Superhard Materials presents up-to-date results of basic and applied research on production, properties, and applications of superhard materials and related tools. It publishes the results of fundamental research on physicochemical processes of forming and growth of single-crystal, polycrystalline, and dispersed materials, diamond and diamond-like films; developments of methods for spontaneous and controlled synthesis of superhard materials and methods for static, explosive and epitaxial synthesis. The focus of the journal is large single crystals of synthetic diamonds; elite grinding powders and micron powders of synthetic diamonds and cubic boron nitride; polycrystalline and composite superhard materials based on diamond and cubic boron nitride; diamond and carbide tools for highly efficient metal-working, boring, stone-working, coal mining and geological exploration; articles of ceramic; polishing pastes for high-precision optics; precision lathes for diamond turning; technologies of precise machining of metals, glass, and ceramics. The journal covers all fundamental and technological aspects of synthesis, characterization, properties, devices and applications of these materials. The journal welcomes manuscripts from all countries in the English language.
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