{"title":"T1 Relaxation of Methane in Mixtures with Gaseous Water","authors":"Harm Ridder*, Wolfgang Dreher and Jorg Thöming, ","doi":"10.1021/acsmeasuresciau.4c00001","DOIUrl":null,"url":null,"abstract":"<p >Synthetic, ecofriendly fuels and chemicals can be produced through Power-To-X (PtX) processes. To study such catalytic processes operando and spatially resolved, magnetic resonance imaging (MRI) is a versatile tool. A main issue in the application of MRI in reactive studies is a lack of knowledge about how the gathered signals can be interpreted into reaction data like temperature or species concentration. In this work, the interaction of methane and gaseous water is studied regarding their longitudinal relaxation time <i>T</i><sub>1</sub> and the chemical shift. To this end, defined quantities of methane-water mixtures were sealed in glass tubes and probed at temperatures between 130 and 360 °C and pressures from 6 to 20 bar. From the obtained <i>T</i><sub>1</sub> relaxation times, the collision cross section of methane with water σ<sub><i>j</i>,CH<sub>4</sub>-H<sub>2</sub>O</sub> is derived, which can be used to estimate the temperature and molar concentration of methane during the methanation reaction. The obtained <i>T</i><sub>1</sub> relaxation times can additionally be used to improve the timing of MRI sequences involving water vapor or methane. Further, details about the measurement workflow and tube preparation are shared.</p>","PeriodicalId":29800,"journal":{"name":"ACS Measurement Science Au","volume":null,"pages":null},"PeriodicalIF":4.6000,"publicationDate":"2024-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsmeasuresciau.4c00001","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Measurement Science Au","FirstCategoryId":"1085","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsmeasuresciau.4c00001","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Synthetic, ecofriendly fuels and chemicals can be produced through Power-To-X (PtX) processes. To study such catalytic processes operando and spatially resolved, magnetic resonance imaging (MRI) is a versatile tool. A main issue in the application of MRI in reactive studies is a lack of knowledge about how the gathered signals can be interpreted into reaction data like temperature or species concentration. In this work, the interaction of methane and gaseous water is studied regarding their longitudinal relaxation time T1 and the chemical shift. To this end, defined quantities of methane-water mixtures were sealed in glass tubes and probed at temperatures between 130 and 360 °C and pressures from 6 to 20 bar. From the obtained T1 relaxation times, the collision cross section of methane with water σj,CH4-H2O is derived, which can be used to estimate the temperature and molar concentration of methane during the methanation reaction. The obtained T1 relaxation times can additionally be used to improve the timing of MRI sequences involving water vapor or methane. Further, details about the measurement workflow and tube preparation are shared.
期刊介绍:
ACS Measurement Science Au is an open access journal that publishes experimental computational or theoretical research in all areas of chemical measurement science. Short letters comprehensive articles reviews and perspectives are welcome on topics that report on any phase of analytical operations including sampling measurement and data analysis. This includes:Chemical Reactions and SelectivityChemometrics and Data ProcessingElectrochemistryElemental and Molecular CharacterizationImagingInstrumentationMass SpectrometryMicroscale and Nanoscale systemsOmics (Genomics Proteomics Metabonomics Metabolomics and Bioinformatics)Sensors and Sensing (Biosensors Chemical Sensors Gas Sensors Intracellular Sensors Single-Molecule Sensors Cell Chips Arrays Microfluidic Devices)SeparationsSpectroscopySurface analysisPapers dealing with established methods need to offer a significantly improved original application of the method.