Preparation of aluminum fluoride from carbon residue in aluminum electrolysis cell by roasting-leaching method

Abstract

The carbon residue is a hazardous waste generated by the aluminum electrolysis production process, which contains a large amount of electrolyte fluoride salts. In order to recover the electrolyte components in carbon residue, this paper proposes a new method of using carbon residue to prepare aluminum fluoride by converting Na₅Al₃F₁₄ and Na₃AlF₆ in carbon residue into aluminum fluoride to realize the recycling of fluoride in carbon residue. In the initial step, optimal parameters for carbon removal during roasting have been determined, including an oxygen flow rate of 7 g/min, a roasting temperature of 670 °C, and a roasting time of 80 min. The roasted clinker is obtained, and the removal rate of carbon reaches 99.95 % while the loss rate of fluorine is 0.48 %. In the second step, the mix anhydrous Al₂(SO₄)₃ with roasted clinker for roasting. The optimal roasting temperature of 670 °C, the time of 10 min, and the mass ratio of anhydrous Al₂(SO₄)₃ to roasted clinker of 5:5 could convert fluoride to AlF₃ products, with a conversion rate of 99.76 % and a loss rate of fluorine of 1.05 %. Finally, by removing sulfate impurities through water leaching for 15 min at 35 °C and with a liquid-solid ratio of 6 ml/g, the loss rate of fluorine is 3.98 %. This process yields AlF₃ with a purity of 94.30 %. The recovery rate of fluorine in the whole process is 94.56 %, which successfully achieves the recycling of fluorine in the carbon residue to obtain AlF₃ products.