Composite Materials Based on Polytetrafluoroethylene with SiO2 and BaTiO3 Inorganic Fillers

IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, CERAMICS Glass Physics and Chemistry Pub Date : 2023-12-01 DOI:10.1134/s1087659623601089
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Abstract

Polymer dielectric composites consisting of polytetrafluoroethylene, silicon dioxide and barium titanate mixed in various proportions were successfully synthesized by low-temperature sintering. The structure of the obtained composite samples was studied by the X-ray diffraction, the electron microscopy, and the weight method. Electrical characteristics (dielectric permittivity and losses) of samples were investigated at a frequency of 1 MHz. According to structural analysis, the synthesized samples are a mixture of amorphous polytetrafluoroethylene and silicon dioxide, and crystalline ferroelectric BaTiO3, the ratio of which determines the electrical properties of the composites. Depending on the content of barium titanate, the studied samples show a permittivity from 4 to 6.5 with a dielectric loss level of 0.06–0.14. It is shown that the significant influence on the dielectric properties of the polytetrafluoroethylene/silicon dioxide/barium titanate system is exerted by heat treatment modes.

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基于聚四氟乙烯与 SiO2 和 BaTiO3 无机填料的复合材料
摘要 采用低温烧结法成功合成了由聚四氟乙烯、二氧化硅和钛酸钡按不同比例混合而成的聚合物介电复合材料。通过 X 射线衍射、电子显微镜和重量法研究了所得复合材料样品的结构。研究了样品在 1 MHz 频率下的电特性(介电常数和损耗)。根据结构分析,合成样品是无定形聚四氟乙烯和二氧化硅与结晶铁电体 BaTiO3 的混合物,两者的比例决定了复合材料的电特性。根据钛酸钡含量的不同,所研究的样品显示出 4 至 6.5 的介电系数,介电损耗水平为 0.06-0.14。研究表明,热处理模式对聚四氟乙烯/二氧化硅/钛酸钡系统的介电性能有重大影响。
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来源期刊
Glass Physics and Chemistry
Glass Physics and Chemistry 工程技术-材料科学:硅酸盐
CiteScore
1.20
自引率
14.30%
发文量
46
审稿时长
6-12 weeks
期刊介绍: Glass Physics and Chemistry presents results of research on the inorganic and physical chemistry of glass, ceramics, nanoparticles, nanocomposites, and high-temperature oxides and coatings. The journal welcomes manuscripts from all countries in the English or Russian language.
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