Studies on Photocatalytic Degradation for Organic Pollutants by TiO2/Au Composite and its Antibacterial Properties

IF 0.7 4区 工程技术 Q4 ENGINEERING, CHEMICAL Theoretical Foundations of Chemical Engineering Pub Date : 2024-03-10 DOI:10.1134/S0040579523330114
Qijie Xu, Zhun Liu
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Abstract

TiO2/Au had been prepared readily from tetrabutyl titanate and chloroauric acid by in situ solvothermal method. SEM, XRD, UV-vis, FTIR, etc were used for characterizing the morphology, crystal structure, and optical performance of TiO2 and TiO2/Au. The photocatalytic degradation performance on methyl orange and antibacterial properties against Escherichia coli of TiO2 and TiO2/Au were studied. The results showed that the TiO2/Au both possessed superior photocatalytic properties under simulated or nature sunlight. The photocatalytic degradation rate of TiO2/Au on methyl orange was up to 91.57% that was obviously better than TiO2 (65.13%). Moreover, TiO2 and TiO2/Au had significant antibacterial properties against Escherichia coli, and the inhibition rate was up to 99.89%. The activity of TiO2 and TiO2/Au was tested by ESR and H2-TPR for analyzing the mechanism of the improvement of the photocatalytic activity and antibacterial properties.

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二氧化钛/金复合材料对有机污染物的光催化降解及其抗菌性能研究
摘要 以钛酸四丁酯和氯金酸为原料,采用原位溶热法制备了 TiO2/Au。利用 SEM、XRD、UV-vis、FTIR 等对 TiO2 和 TiO2/Au 的形貌、晶体结构和光学性能进行了表征。研究了 TiO2 和 TiO2/Au 对甲基橙的光催化降解性能和对大肠杆菌的抗菌性能。结果表明,在模拟或自然阳光下,TiO2/Au 都具有优异的光催化性能。TiO2/Au 对甲基橙的光催化降解率高达 91.57%,明显优于 TiO2(65.13%)。此外,TiO2 和 TiO2/Au 对大肠杆菌有明显的抗菌作用,抑菌率高达 99.89%。通过 ESR 和 H2-TPR 测试了 TiO2 和 TiO2/Au 的活性,分析了光催化活性和抗菌性提高的机理。
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来源期刊
CiteScore
1.20
自引率
25.00%
发文量
70
审稿时长
24 months
期刊介绍: Theoretical Foundations of Chemical Engineering is a comprehensive journal covering all aspects of theoretical and applied research in chemical engineering, including transport phenomena; surface phenomena; processes of mixture separation; theory and methods of chemical reactor design; combined processes and multifunctional reactors; hydromechanic, thermal, diffusion, and chemical processes and apparatus, membrane processes and reactors; biotechnology; dispersed systems; nanotechnologies; process intensification; information modeling and analysis; energy- and resource-saving processes; environmentally clean processes and technologies.
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