Thomas E. Shaw, Justin Arami, Jean-François Ayme, Jean-Marie Lehn and Titel Jurca
{"title":"Dynamic mechanochemistry: accelerated self-sorting of two imine-based metal complexes under solvent-free mechanochemical conditions†","authors":"Thomas E. Shaw, Justin Arami, Jean-François Ayme, Jean-Marie Lehn and Titel Jurca","doi":"10.1039/D3MR00021D","DOIUrl":null,"url":null,"abstract":"<p >Self-sorting of two imine-based Cu(<small>I</small>) and Fe(<small>II</small>) coordination complexes from a six-component reagent library has been achieved through solvent-free mechanochemistry. The reaction proceeds rapidly, yielding the thermodynamically favored products in less than 24 hours. The results point to the potential of mechanochemistry to achieve increasingly complex multi-metallic systems through one-pot protocols.</p>","PeriodicalId":101140,"journal":{"name":"RSC Mechanochemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/mr/d3mr00021d?page=search","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"RSC Mechanochemistry","FirstCategoryId":"1085","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/mr/d3mr00021d","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Self-sorting of two imine-based Cu(I) and Fe(II) coordination complexes from a six-component reagent library has been achieved through solvent-free mechanochemistry. The reaction proceeds rapidly, yielding the thermodynamically favored products in less than 24 hours. The results point to the potential of mechanochemistry to achieve increasingly complex multi-metallic systems through one-pot protocols.
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