Corrosion Tests of Domestic and Imported Chromium-Containing and Baddelyite–Corundum Refractories in Borosilicate Glass Melts

IF 0.9 Q4 CHEMISTRY, INORGANIC & NUCLEAR Radiochemistry Pub Date : 2024-03-12 DOI:10.1134/s1066362223070202
S. M. Shaydullin, P. V. Kozlov, M. B. Remizov
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Abstract

TThe paper justifies great practical relevance of the problem of corrosion and erosion resistance of the refractories used as a structural element in direct electric heating furnaces intended for high-level waste vitrification. The list of the main promising materials is provided, as well as the algorithm of assessing their resistance to borosilicate melts during operation of electric furnaces. Corrosion tests of the refractory materials were carried out under static and dynamic conditions in low-melting borosilicate glass and in the melt of borosilicate glass containing simulated liquid high-level waste (HLW). The refractories that are most resistant to the glass melt under conditions of HLW solidification were identified. The results obtained will be useful for selecting the lining material for removable and small-size melters.

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国产和进口含铬耐火材料和巴德锂刚玉耐火材料在硼硅酸盐玻璃熔体中的腐蚀试验
摘要本文论证了在用于高浓度废物玻璃化的直接电加热炉中作为结构元件的耐火材料的抗腐蚀和抗侵蚀性问题的重大现实意义。报告提供了主要的有前途材料清单,以及评估这些材料在电炉运行期间对硼硅酸盐熔体的耐腐蚀性的算法。在低熔硼硅酸盐玻璃和含有模拟液态高放射性废物(HLW)的硼硅酸盐玻璃熔体的静态和动态条件下,对耐火材料进行了腐蚀测试。确定了在高放射性废物凝固条件下最耐受玻璃熔体的耐火材料。所获得的结果将有助于为可移动式和小型熔化器选择衬里材料。
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来源期刊
Radiochemistry
Radiochemistry CHEMISTRY, INORGANIC & NUCLEAR-
CiteScore
1.30
自引率
33.30%
发文量
51
期刊介绍: Radiochemistry  is a journal that covers the theoretical and applied aspects of radiochemistry, including basic nuclear physical properties of radionuclides; chemistry of radioactive elements and their compounds; the occurrence and behavior of natural and artificial radionuclides in the environment; nuclear fuel cycle; radiochemical analysis methods and devices; production and isolation of radionuclides, synthesis of labeled compounds, new applications of radioactive tracers; radiochemical aspects of nuclear medicine; radiation chemistry and after-effects of nuclear transformations.
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