Growing ZnS nanoparticles on novel expanded perlite-butadiene rubber composite by SILAR method

IF 1.2 4区化学 Q4 POLYMER SCIENCE Journal of Rubber Research Pub Date : 2024-03-18 DOI:10.1007/s42464-024-00246-6

Nada Edres, Irada Buniyatzadeh, Solmaz Aliyeva, Goncha Eyvazova, Nurlana Binnetova, Naila Guliyeva, Sevinj Mammadyarova, Rasim Alosmanov

{"title":"Growing ZnS nanoparticles on novel expanded perlite-butadiene rubber composite by SILAR method","authors":"Nada Edres, Irada Buniyatzadeh, Solmaz Aliyeva, Goncha Eyvazova, Nurlana Binnetova, Naila Guliyeva, Sevinj Mammadyarova, Rasim Alosmanov","doi":"10.1007/s42464-024-00246-6","DOIUrl":null,"url":null,"abstract":"<div><p>The article focuses on synthesising a new nanocomposite incorporating ZnS filler and investigating its structure, optical properties and specific electrical conductivity. In this study, expanded perlite (EP) and butadiene rubber (BR) underwent simultaneous oxidative chlorophosphorylation and subsequent hydrolysis. ZnS nanoparticles were then grown on the crosslinked/ion-exchange composite (EP-PhBR) using the Successive Ionic Layer Adsorption and Reaction (SILAR) method, resulting in the ZnS/EP-PhBR nanocomposite. The structure of the nanocomposite was characterised through UV-Vis spectroscopy and X-ray diffraction analysis. Embedding ZnS nanoparticles in EP-PhBR caused a reduction in the optical band gap from 3.18 eV to 3.045 eV, signifying increased disorder in ZnS nanoparticles due to alterations in the nanocomposite’s intermolecular structure. XRD studies revealed cubic crystal-structured ZnS nanoparticles with an average size of approximately 3 nm in the ZnS/EP-PhBR nanocomposite. The specific electrical conductivity (σ) at ambient temperature demonstrated the enhanced crystallinity of EP-PhBR, attributed to interfacial interactions with ZnS nanoparticles and the developed nanolayers. The ZnS/EP-PhBR nanocomposite exhibited favourable properties, making it a promising material for photocatalysis and solar cell applications.</p></div>","PeriodicalId":662,"journal":{"name":"Journal of Rubber Research","volume":"27 3","pages":"299 - 308"},"PeriodicalIF":1.2000,"publicationDate":"2024-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Rubber Research","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s42464-024-00246-6","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}

引用次数: 0

Abstract

The article focuses on synthesising a new nanocomposite incorporating ZnS filler and investigating its structure, optical properties and specific electrical conductivity. In this study, expanded perlite (EP) and butadiene rubber (BR) underwent simultaneous oxidative chlorophosphorylation and subsequent hydrolysis. ZnS nanoparticles were then grown on the crosslinked/ion-exchange composite (EP-PhBR) using the Successive Ionic Layer Adsorption and Reaction (SILAR) method, resulting in the ZnS/EP-PhBR nanocomposite. The structure of the nanocomposite was characterised through UV-Vis spectroscopy and X-ray diffraction analysis. Embedding ZnS nanoparticles in EP-PhBR caused a reduction in the optical band gap from 3.18 eV to 3.045 eV, signifying increased disorder in ZnS nanoparticles due to alterations in the nanocomposite’s intermolecular structure. XRD studies revealed cubic crystal-structured ZnS nanoparticles with an average size of approximately 3 nm in the ZnS/EP-PhBR nanocomposite. The specific electrical conductivity (σ) at ambient temperature demonstrated the enhanced crystallinity of EP-PhBR, attributed to interfacial interactions with ZnS nanoparticles and the developed nanolayers. The ZnS/EP-PhBR nanocomposite exhibited favourable properties, making it a promising material for photocatalysis and solar cell applications.

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

利用 SILAR 法在新型膨胀珍珠棉-丁二烯橡胶复合材料上生长 ZnS 纳米粒子

摘要本文主要研究了一种含有 ZnS 填料的新型纳米复合材料的合成，并对其结构、光学特性和比电导率进行了研究。在这项研究中，膨胀珍珠岩（EP）和丁二烯橡胶（BR）同时进行了氧化氯磷酸化和随后的水解。然后采用连续离子层吸附和反应（SILAR）方法在交联/离子交换复合材料（EP-PhBR）上生长 ZnS 纳米颗粒，从而得到 ZnS/EP-PhBR 纳米复合材料。通过紫外可见光谱和 X 射线衍射分析对纳米复合材料的结构进行了表征。在 EP-PhBR 中嵌入 ZnS 纳米粒子会导致光带隙从 3.18 eV 减小到 3.045 eV，这表明由于纳米复合材料分子间结构的改变，ZnS 纳米粒子的无序性增加。XRD 研究显示，ZnS/EP-PhBR 纳米复合材料中的 ZnS 纳米粒子为立方晶体结构，平均尺寸约为 3 nm。环境温度下的比电导率（σ）表明 EP-PhBR 的结晶性增强，这归因于 ZnS 纳米颗粒与所形成的纳米层之间的界面相互作用。ZnS/EP-PhBR 纳米复合材料表现出良好的特性，使其成为光催化和太阳能电池应用的理想材料。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文去求助

来源期刊

Journal of Rubber Research 化学-高分子科学

自引率

15.40%

发文量

审稿时长

3 months

期刊介绍： The Journal of Rubber Research is devoted to both natural and synthetic rubbers, as well as to related disciplines. The scope of the journal encompasses all aspects of rubber from the core disciplines of biology, physics and chemistry, as well as economics. As a specialised field, rubber science includes within its niche a vast potential of innovative and value-added research areas yet to be explored. This peer reviewed publication focuses on the results of active experimental research and authoritative reviews on all aspects of rubber science. The Journal of Rubber Research welcomes research on: the upstream, including crop management, crop improvement and protection, and biotechnology; the midstream, including processing and effluent management; the downstream, including rubber engineering and product design, advanced rubber technology, latex science and technology, and chemistry and materials exploratory; economics, including the economics of rubber production, consumption, and market analysis. The Journal of Rubber Research serves to build a collective knowledge base while communicating information and validating the quality of research within the discipline, and bringing together work from experts in rubber science and related disciplines. Scientists in both academia and industry involved in researching and working with all aspects of rubber will find this journal to be both source of information and a gateway for their own publications.