Investigation of the Mechanical and Chemical Stability of Superhydrophobic Coatings Based on Reactive Copolymers of Glycidyl Methacrylate and Fluoroalkyl Methacrylates

IF 1.1 4区 化学 Q4 CHEMISTRY, PHYSICAL Colloid Journal Pub Date : 2024-03-18 DOI:10.1134/S1061933X23601208
V. V. Klimov, O. V. Kolyaganova, E. V. Bryuzgin, A. V. Navrotskiy, I. A. Novakov
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Abstract

This work is devoted to studying the stability of polymer coatings formed from reactive copolymers of glycidyl methacrylate and fluoroalkyl methacrylates and applied onto textured aluminum and cotton textile surfaces. The stability is determined with respect to the action of aggressive media and mechanical stress. The resulting coatings provide the achievement of long-term stable heterogeneous wetting with initial contact angles as large as 170°, thus preventing the penetration of corrosive agents into the hierarchical structure. The study has shown the influence of the composition of the reactive copolymers containing 3–7 fluorine atoms in a monomer unit on the stability of the polymer coatings with respect to the prolonged exposure to media with different acidities, as well as to cavitation, and abrasive wear.

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基于甲基丙烯酸缩水甘油酯和甲基丙烯酸氟烷基酯反应共聚物的超疏水涂层的机械和化学稳定性研究
摘要--这项工作致力于研究由甲基丙烯酸缩水甘油酯和甲基丙烯酸氟烷基酯的反应共聚物形成的聚合物涂层在纹理铝和棉纺织品表面上的稳定性。涂层的稳定性取决于侵蚀性介质和机械应力的作用。所得涂层可实现长期稳定的异质润湿,初始接触角可大至 170°,从而防止腐蚀剂渗入分层结构。研究表明,单体单元中含有 3-7 个氟原子的活性共聚物的组成对聚合物涂层在长期暴露于不同酸度的介质以及气蚀和磨料磨损下的稳定性有影响。
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来源期刊
Colloid Journal
Colloid Journal 化学-物理化学
CiteScore
2.20
自引率
18.20%
发文量
36
审稿时长
6-12 weeks
期刊介绍: Colloid Journal (Kolloidnyi Zhurnal) is the only journal in Russia that publishes the results of research in the area of chemical science dealing with the disperse state of matter and surface phenomena in disperse systems. The journal covers experimental and theoretical works on a great variety of colloid and surface phenomena: the structure and properties of interfaces; adsorption phenomena and structure of adsorption layers of surfactants; capillary phenomena; wetting films; wetting and spreading; and detergency. The formation of colloid systems, their molecular-kinetic and optical properties, surface forces, interaction of colloidal particles, stabilization, and criteria of stability loss of different disperse systems (lyosols and aerosols, suspensions, emulsions, foams, and micellar systems) are also topics of the journal. Colloid Journal also includes the phenomena of electro- and diffusiophoresis, electro- and thermoosmosis, and capillary and reverse osmosis, i.e., phenomena dealing with the existence of diffusion layers of molecules and ions in the vicinity of the interface.
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