Development of Materials Based on Poly(lactic acid) and Copper(II) Sulfate Impregnated by the Crazing Method

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-03-18 DOI:10.1134/S1061933X23601178
S. D. Brovina, E. E. Mastalygina, E. S. Trofimchuk, A. A. Popov
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Abstract

The common approach to creating antimicrobial polymer materials is the distribution of a bactericidal additive in a material by mixing the additive with a solution or a melt of the polymer. This work proposes the method introducing of copper(II) sulfate, which has antimicrobial properties, into a poly(lactic acid) film by forced impregnation of a salt solution via the crazing mechanism. CuSO4 has been found to be uniformly distributed in the bulk of the polymer in the form of particles with sizes of about 100 nm. In the course of the structural modification, the surface of the polymer film becomes rougher and more hydrophobic. The water contact angle increases from 40° to 60°–65°. The incorporation of CuSO4 does not affect the surface properties but has a reinforcing effect on the polymer matrix as is evident from tensile tests (strength and elongation at break increase by 2.5 and 1.4 times, respectively).

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用压裂法开发基于聚(乳酸)和硫酸铜(II)浸渍的材料
摘要 制造抗菌聚合物材料的常见方法是将杀菌添加剂与聚合物溶液或熔体混合,从而在材料中分布杀菌添加剂。本研究提出了通过裂纹机制将具有抗菌特性的硫酸铜(II)通过盐溶液强制浸渍的方法引入聚乳酸薄膜中。研究发现,硫酸铜以大小约为 100 纳米的颗粒形式均匀地分布在聚合物的主体中。在结构改性的过程中,聚合物薄膜的表面变得更加粗糙和疏水。水接触角从 40°增加到 60°-65°。CuSO4 的加入不会影响表面特性,但对聚合物基体有增强作用,这一点从拉伸试验中可以明显看出(强度和断裂伸长率分别增加了 2.5 倍和 1.4 倍)。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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