Analysis of the Cross-Contamination of explosive canine training aids during manufacturing and storage

IF 2.6 3区 医学 Q2 CHEMISTRY, ANALYTICAL Forensic Chemistry Pub Date : 2024-03-19 DOI:10.1016/j.forc.2024.100571
Kymeri Davis, John V. Goodpaster
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Abstract

Explosive detecting canines should be trained using real explosive materials that have minimal contamination by other explosive odors to ensure accurate identification of potential threats. Therefore, the potential for cross-contamination between training aids is of importance. There are various storage methods in use by canine handlers, such as plastic and cloth bags, but these can lead to cross-contamination between training aids during storage. Alternatively, odor-permeable membrane devices (OPMD) may store training aides and be used as a delivery device. OPMDs allow for volatile compounds from the training aids to be released during training while helping to prevent contaminants from entering the device. However, the amount of contamination in a training aid upon receipt from a vendor is outside the control of canine handlers. To test the initial cross-contamination levels of training aids, 11 explosive materials were ordered from three different vendors. A 1-gram sample of each was collected and analyzed using gas chromatography – mass spectrometry. In several cases, explosive materials that are commercially available already exhibit elevated levels of contamination. This indicates that training aids must be acquiring contamination during manufacturing and/or storage at the vendor facility. The cross-contamination of explosive canine training aids stored in OPMDs was further evaluated and compared to traditional storage methods by storing various combinations of storage containers with explosives and using activated charcoal strips to collect the volatile compounds. Only one type of storage container, a Velcro bag, showed evidence of contamination.

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爆炸性警犬训练器材在制造和储存过程中的交叉污染分析
应使用受其他爆炸物气味污染最小的真实爆炸物来训练爆炸物探测警犬,以确保准确识别潜在威胁。因此,训练用具之间交叉污染的可能性非常重要。警犬训导员使用的储存方法多种多样,如塑料袋和布袋,但在储存过程中可能会导致训练器材之间的交叉污染。另外,气味渗透膜装置(OPMD)也可以储存训练辅助器材并用作输送装置。透气膜装置允许训练辅助器材中的挥发性化合物在训练过程中释放出来,同时有助于防止污染物进入装置。但是,从供应商处收到的训练辅助用品的污染量超出了警犬饲养员的控制范围。为了测试训练器材的初始交叉污染水平,我们从三个不同的供应商处订购了 11 种爆炸材料。收集每种材料 1 克的样本,并使用气相色谱-质谱法进行分析。在几种情况下,市场上销售的爆炸材料已经显示出较高的污染水平。这表明,训练用具一定是在生产和/或储存过程中被供应商设施污染了。通过在不同组合的储存容器中储存爆炸物并使用活性炭条收集挥发性化合物,进一步评估了储存在 OPMD 中的警犬爆炸物训练器材的交叉污染情况,并与传统储存方法进行了比较。只有一种存储容器(尼龙搭扣袋)出现了污染迹象。
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来源期刊
Forensic Chemistry
Forensic Chemistry CHEMISTRY, ANALYTICAL-
CiteScore
5.70
自引率
14.80%
发文量
65
审稿时长
46 days
期刊介绍: Forensic Chemistry publishes high quality manuscripts focusing on the theory, research and application of any chemical science to forensic analysis. The scope of the journal includes fundamental advancements that result in a better understanding of the evidentiary significance derived from the physical and chemical analysis of materials. The scope of Forensic Chemistry will also include the application and or development of any molecular and atomic spectrochemical technique, electrochemical techniques, sensors, surface characterization techniques, mass spectrometry, nuclear magnetic resonance, chemometrics and statistics, and separation sciences (e.g. chromatography) that provide insight into the forensic analysis of materials. Evidential topics of interest to the journal include, but are not limited to, fingerprint analysis, drug analysis, ignitable liquid residue analysis, explosives detection and analysis, the characterization and comparison of trace evidence (glass, fibers, paints and polymers, tapes, soils and other materials), ink and paper analysis, gunshot residue analysis, synthetic pathways for drugs, toxicology and the analysis and chemistry associated with the components of fingermarks. The journal is particularly interested in receiving manuscripts that report advances in the forensic interpretation of chemical evidence. Technology Readiness Level: When submitting an article to Forensic Chemistry, all authors will be asked to self-assign a Technology Readiness Level (TRL) to their article. The purpose of the TRL system is to help readers understand the level of maturity of an idea or method, to help track the evolution of readiness of a given technique or method, and to help filter published articles by the expected ease of implementation in an operation setting within a crime lab.
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