Bio-based templates for generating hierarchical zeolites: an overview for greener synthesis pathway

IF 2.5 4区 材料科学 Q2 CHEMISTRY, APPLIED Journal of Porous Materials Pub Date : 2024-03-23 DOI:10.1007/s10934-024-01586-9
Arxhel S. F. Nanda, Grandprix T. M. Kadja
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Abstract

In general, hierarchical zeolite synthesis will produce waste, which will cause many problems for environmental pollution. The waste that comes from the synthesis of zeolites, such as the use of hazardous chemicals from the use of many solvents, additional templates, silica sources used, and other precursors that are not environmentally friendly. One solution to the problem is to use bio-based templates. The advantage of using this bio-based template is that it is environmentally friendly, reduces dependence on hazardous chemicals, and supports sustainability for bio-based templates such as carbohydrates, chitin, and others. The use of the previously mentioned templates in zeolite synthesis can produce hierarchical pores, high crystallinity, and catalytic properties that are not inferior to conventional zeolites obtained, and more cost-effective. The efforts are expected to fulfill the principles of green chemistry, which prioritizes the environment to provide better prospects for the synthesis of hierarchical zeolites in the future.

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生成分层沸石的生物基模板:绿色合成途径概述
一般来说,分层沸石合成会产生废弃物,造成许多环境污染问题。沸石合成过程中产生的废弃物,如使用多种溶剂产生的有害化学物质、额外的模板、使用的二氧化硅来源以及其他不环保的前体。解决这一问题的方法之一是使用生物基模板。使用这种生物基模板的优点是环保、减少对危险化学品的依赖,并支持碳水化合物、甲壳素等生物基模板的可持续发展。在沸石合成中使用前面提到的模板,可以产生分层孔隙、高结晶度和催化性能,这些性能并不逊色于传统的沸石,而且更具成本效益。这些努力有望实现环境优先的绿色化学原则,为未来合成分层沸石提供更好的前景。
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来源期刊
Journal of Porous Materials
Journal of Porous Materials 工程技术-材料科学:综合
CiteScore
4.80
自引率
7.70%
发文量
203
审稿时长
2.6 months
期刊介绍: The Journal of Porous Materials is an interdisciplinary and international periodical devoted to all types of porous materials. Its aim is the rapid publication of high quality, peer-reviewed papers focused on the synthesis, processing, characterization and property evaluation of all porous materials. The objective is to establish a unique journal that will serve as a principal means of communication for the growing interdisciplinary field of porous materials. Porous materials include microporous materials with 50 nm pores. Examples of microporous materials are natural and synthetic molecular sieves, cationic and anionic clays, pillared clays, tobermorites, pillared Zr and Ti phosphates, spherosilicates, carbons, porous polymers, xerogels, etc. Mesoporous materials include synthetic molecular sieves, xerogels, aerogels, glasses, glass ceramics, porous polymers, etc.; while macroporous materials include ceramics, glass ceramics, porous polymers, aerogels, cement, etc. The porous materials can be crystalline, semicrystalline or noncrystalline, or combinations thereof. They can also be either organic, inorganic, or their composites. The overall objective of the journal is the establishment of one main forum covering the basic and applied aspects of all porous materials.
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Correction: One-step synthesis of CuO/MCM-41 nanocomposites and their application in photocatalytic degradation of dyes Modification of SBA-15 for stabilizing supported oxides Lotus leaf-derived capacitive carbon for zinc-ion hybrid supercapacitors prepared by one-step molten salt carbonization Influence of various templates on the performance of MFI zeolite in catalytic synthesis of trioxane Facile synthesis of copper sulfide loaded mesoporous organosilica nanospheres with a triple-shelled hollow structure
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