Petrogenesis of the Early Paleogene North Island Syenite Complex, Seychelles

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-03-21 DOI:10.2475/001c.94773
J. Shellnutt, Tung-Yi Lee, Yoshiyuki Iizuka, Hao-Yang Lee, Chi Thi Pham, Kenshi Suga
{"title":"Petrogenesis of the Early Paleogene North Island Syenite Complex, Seychelles","authors":"J. Shellnutt, Tung-Yi Lee, Yoshiyuki Iizuka, Hao-Yang Lee, Chi Thi Pham, Kenshi Suga","doi":"10.2475/001c.94773","DOIUrl":null,"url":null,"abstract":"The Early Paleogene (63.65 ± 0.52 Ma, 63.11 ± 0.45 Ma) North Island syenitic complex of the Seychelles microcontinent is composed principally of diorite (SiO2 ≈ 57 wt%), syenite (SiO2 = 61–65 wt%), and microsyenite (SiO2 = ∼70 wt%). The rocks are metaluminous, ferroan, and alkalic, and are compositionally similar to the A1-type granitoids. The trace element compositions of the syenitic rocks show minor spatial variability between the eastern (Congoment, Bernica) and western portions (Grand’Anse, Mt. Des Cèdres) of the island. The whole rock Sr-Nd (87Sr/86Sri = 0.704095–0.707533; εNd(t) = +1.2–+1.9) and zircon Hf ( εHf(t) = +2.1–+8.4) isotopes are indicative of a juvenile magma source. The low Th/NbPM (0.3–1.5) and high Nb/U (30.9–109) ratios do not indicate a crustal origin of the rocks nor do they suggest crustal contamination was significant. Hydrous fractional crystallization modeling shows that a mafic alkaline parental magma can yield residual liquid compositions similar to the diorites and syenites under reducing conditions ( ΔFMQ = −1) at a pressure of 0.3 GPa. However, feldspar accumulation likely occurred as some rocks have elevated Eu/Eu* (>1.1) values. The emplacement of the North Island complex is contemporaneous with the eruption of the Deccan Traps and rifting of the Seychelles microcontinent from India. Rifting and magmatism was likely related to the passage of the Indian plate over the Réunion hotspot. The modeling results of the study demonstrate that crystallization pressure has an influence on whether basalt-derived A-type granitoids will evolve to metaluminous or peralkaline compositions.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":" 23","pages":""},"PeriodicalIF":17.7000,"publicationDate":"2024-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"89","ListUrlMain":"https://doi.org/10.2475/001c.94773","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

The Early Paleogene (63.65 ± 0.52 Ma, 63.11 ± 0.45 Ma) North Island syenitic complex of the Seychelles microcontinent is composed principally of diorite (SiO2 ≈ 57 wt%), syenite (SiO2 = 61–65 wt%), and microsyenite (SiO2 = ∼70 wt%). The rocks are metaluminous, ferroan, and alkalic, and are compositionally similar to the A1-type granitoids. The trace element compositions of the syenitic rocks show minor spatial variability between the eastern (Congoment, Bernica) and western portions (Grand’Anse, Mt. Des Cèdres) of the island. The whole rock Sr-Nd (87Sr/86Sri = 0.704095–0.707533; εNd(t) = +1.2–+1.9) and zircon Hf ( εHf(t) = +2.1–+8.4) isotopes are indicative of a juvenile magma source. The low Th/NbPM (0.3–1.5) and high Nb/U (30.9–109) ratios do not indicate a crustal origin of the rocks nor do they suggest crustal contamination was significant. Hydrous fractional crystallization modeling shows that a mafic alkaline parental magma can yield residual liquid compositions similar to the diorites and syenites under reducing conditions ( ΔFMQ = −1) at a pressure of 0.3 GPa. However, feldspar accumulation likely occurred as some rocks have elevated Eu/Eu* (>1.1) values. The emplacement of the North Island complex is contemporaneous with the eruption of the Deccan Traps and rifting of the Seychelles microcontinent from India. Rifting and magmatism was likely related to the passage of the Indian plate over the Réunion hotspot. The modeling results of the study demonstrate that crystallization pressure has an influence on whether basalt-derived A-type granitoids will evolve to metaluminous or peralkaline compositions.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
塞舌尔早古新世北岛闪长岩群的岩石成因
塞舌尔微大陆的早古近纪(63.65 ± 0.52 Ma, 63.11 ± 0.45 Ma)北岛正长岩复合体主要由闪长岩(SiO2 ≈ 57 wt%)、正长岩(SiO2 = 61-65 wt%)和微正长岩(SiO2 = ∼ 70 wt%)组成。这些岩石具有金属性、铁性和碱性,在成分上与A1型花岗岩相似。正长岩的微量元素组成在该岛东部(Congoment、Bernica)和西部(Grand'Anse、Mt. Des Cèdres)之间存在微小的空间差异。整块岩石的 Sr-Nd (87Sr/86Sri = 0.704095-0.707533; εNd(t) = +1.2-+1.9 )和锆石 Hf (εHf(t) = +2.1-+8.4)同位素表明是幼年岩浆源。低Th/NbPM(0.3-1.5)和高Nb/U(30.9-109)比值并不表明岩石来源于地壳,也不表明地壳污染严重。水相分块结晶模型显示,在还原条件下(ΔFMQ =-1),0.3 GPa的压力下,黑云母碱性母岩浆可产生与闪长岩和正长岩类似的残余液体成分。然而,由于一些岩石的Eu/Eu*值升高(>1.1),长石很可能发生了堆积。北岛复合体的形成与德干陷阱的喷发和塞舌尔微大陆从印度的断裂同时发生。断裂和岩浆活动很可能与印度板块穿过留尼汪热点有关。该研究的建模结果表明,结晶压力对玄武岩衍生的 A 型花岗岩是演化成金属铝成分还是围岩成分有影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
期刊最新文献
Conjugated Oligoelectrolytes as Optical Probes. Charge State Evolution in Electrocatalysts for Bridging the Activity-Stability Gap in Acidic Oxygen Evolution. Computational and AI-Driven Ecosystem for Structure-Based Covalent Drug Discovery. Metabolic RNA Labeling-Enabled Time-Resolved Single-Cell RNA Sequencing. Multifunctional Guest-Hosting Triple-Stranded Helicates: From Anion Recognition to Quantum Information Applications.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1