Influence of the addition of carbon nanotube on the physical behavior of a lateritic soil from the southwest Amazon

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-03-14 DOI:10.28927/sr.2024.007523
Marcelo Morais, Marcelo Nunes, Carlos Morais, Ricardo Nascimento, A. Rodriguez
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Abstract

In this work we evaluate the physical-mechanical behavior of lateritic soil with addition of carbon nanotubes. The soil was collected in a commercial deposit located in Rio Branco – AC and later characterized through particle size tests, X-Ray Diffraction, X-Ray Dispersion Spectroscopy and Tropical Compressed Miniature essay. The dispersion of nanotubes in solution was carried out and the size of the nanoparticles was verified using Dynamic Light Spreading - DLS, Zeta Potential and PDI. Three percentages of additions (0.05%, 0.1% and 0.2%) of carbon nanotubes were evaluated and compared with the control group according to the parameters of Atterberg limits, real density, dry density maximum and optimum humidity. The results indicate that the soil has a clayey behavior with a medium texture, with the presence of clay mineral kaolinite in its composition and silicon and iron oxides. The dispersion of carbon nanotubes reached particles with an average hydrodynamic diameter of 68.9 nm and Zeta Potential of -24.87 mV and PDI of 0.231, characterizing a solution as moderately dispersed and kinetically stable. The results of the liquidity limit and plasticity tests showed a reduction of 10 and 13%, respectively, with the addition of carbon nanotubes, while for the parameters of plasticity index, real specific mass, maximum dry density and optimal moisture, they did not show significant variation. Carbon nanotubes interact with soils with lateritic behavior, and further studies are essential to better understand the mechanisms behind this interaction.
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添加碳纳米管对亚马逊西南部红土物理特性的影响
在这项工作中,我们对添加了碳纳米管的红土的物理机械性能进行了评估。土壤采集于位于 AC 省 Rio Branco 的一个商业矿床,随后通过粒度测试、X 射线衍射、X 射线色散光谱和热带压缩微型论文对其进行了表征。纳米管在溶液中的分散是通过动态光散射(DLS)、Zeta 电位和 PDI 来验证的。根据阿特伯极限、实际密度、最大干密度和最佳湿度等参数,对碳纳米管的三个添加百分比(0.05%、0.1% 和 0.2%)进行了评估,并与对照组进行了比较。结果表明,土壤具有中等质地的粘土特性,其成分中含有粘土矿物高岭石以及硅和铁的氧化物。碳纳米管的平均流体力学直径为 68.9 nm,Zeta 电位为 -24.87 mV,PDI 为 0.231。流动性极限和可塑性测试结果表明,添加碳纳米管后,流动性极限和可塑性分别降低了 10% 和 13%,而可塑性指数、实际比质量、最大干密度和最佳湿度等参数则没有明显变化。碳纳米管与具有红土特性的土壤相互作用,为了更好地了解这种相互作用背后的机制,进一步的研究是必不可少的。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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